A statistical 'randomised block design' full plant trial of magnetic conditioning of flotation feed was undertaken at Rio Tinto's Northparkes Mine in New South Wales. Magnetic conditioning of flotation feed has been shown to improve the flotation of ,38 mm paramagnetic minerals consistent with selectively aggregating these paramagnetic minerals. The process was evaluated using shift composite samples that were analysed for copper and gold. Because the process targets ,38 mm minerals, all samples were sized and the size-by-size recoveries were calculated for each sample. The size-by-size analysis targeted the effect on fine mineral, reduced the plant noise and shortened the test period required to get statistically significant results. An increase in gold and copper recovery was found in the ,20 mm fraction to a high level of statistical significance. For the .20 and ,38 mm size range, the copper recovery increased to a high level of significance, whereas the increase in gold recovery in this fraction was to a lower statistical significance. There was no statistical improvement in the .38 mm fraction for either metal. Approximately half the copper and gold losses at Northparkes are in the ,20 mm size fraction. While the sulphide copper minerals chalcopyrite and bornite are known to be paramagnetic; gold is not paramagnetic. Gold's response to magnetic conditioning, however, is consistent with a number of literature references where, depending on the gold's mineralogical disposition, gold has been shown to respond to magnetic treatment.
The influence of anodic and cathodic prepolarization of electrodes, containing respectively 0.03, 0.48, and 1.3 percent carbon, in de-aerated N and 0.1 N sulfuric acid at 25 C (77 F) on the subsequent open circuit potential-time curves has been determined. Anodic pretreatment always lowers and cathodic pretreatment raises the initial potential on these curves. Magnitude of the potential shift and time required to resume the rest potential are larger the higher the prepolarizing time. The influence of carbon content and acid concentration is complex. Special experiments have indicated the importance of specimen, and especially solution history, and have permitted an interpretation in terms of polarization diagrams. The most likely explanation is the influence of sulfide or noble metal or metalloid ions derived from the alloy or possibly the solution in altering the number of active anodic sites. This is achieved by an increase in the degree of hydrogen poisoning or by accumulation or plating out of metals or metalloids.
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