Fe-rich carbonatites with a mineral assemblage of ankerite-calcite or siderite are widespread in southern Siberia, Russia. The siderite carbonatites are associated with F-Ba-Sr-REE mineralization and have a 40 Ar/ 39 Ar age of 117.2 ± 1.3 Ma. Melt and fluid inclusions suggest that the carbonatites formed from volatile-rich alkali-and chloride-bearing carbonate melts. Ankeritecalcite carbonatites formed from carbonatite melt at a temperature of more than 790°C. The ferrocarbonatites (the second phase of carbonatite intrusion) formed from a sulfate-carbonate-chloride fluid phase (brine-melt) at >650°C and ≥360 MPa. The brine-melt fluid phase had high concentrations of Fe and LREEs. A subsequent hydrothermal overprint contributed to the formation of economically important barite-Sr-fluorite-REE mineralization in polymict siderite breccia.

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Based on data on the composition of ore-bearing hydrothermal solutions and parameters of ore-forming processes at various antimony and antimony-bearing deposits, which were obtained in studies of fluid inclusions in ore minerals, we investigated the behavior of Sb(III) in the system Sb–Cl–H2S–H2O describing the formation of these deposits. We also performed thermodynamic modeling of native-antimony and stibnite dissolution in sulfide (mHS− = 0.0001−0.1) and chloride (mCl− = 0.1−5) solutions and the joint dissolution of Sb(s)0 and Sb2S3(s) in sulfide-chloride solution (mHS− = 0.01; mCl− = 1) depending on Eh, pH, and temperature. All thermodynamic calculations were carried out using the Chiller computer program. Under the above conditions, stibnite precipitates in acid, weakly acid to neutral, and medium redox solutions, whereas native antimony precipitates before stibnite under more reducing conditions in neutral to alkaline solutions. The metal-bearing capacity of hydrothermal solutions (200–250 °C) of different compositions and origins has been predicted. We have established that the highest capacity is specific for acid (pH = 2–3) high-chloride solutions poor in sulfide sulfur and alkaline (pH = 7–8) low-chloride low-sulfide solutions.

The paper presents new isotope geochronological data for several mineral deposits, ore occurrences, and related igneous bodies (plutons and dikes) in the Verkhoyansk–Kolyma folded area, eastern Yakutia. Twenty-one 40Ar/39Ar mica and four U–Pb zircon dates provide the first age constraints on key metallogenic units in the area. The dating results allow correlation between tectonic, magmatic, and metallogenic events. The sampled mineral deposits within the Adycha–Taryn fault zone in the southeastern Verkhoyansk–Chersky orogen apparently formed at the Jurassic–Cretaceous boundary during the final phase of the collision between the Siberian (North Asian) craton and the Kolyma–Omolon microcontinent (Kupol’noe deposit and the early metallogenic pulse of the Malotarynskoe deposit, ~ 143–144 Ma) and in the latest Early Cretaceous, in the beginning of the orogen collapse (Tallalakh and Dora-Pil’ deposits and the Malotarynskoe late metallogenic pulse, ~ 126 Ma). According to the suggested new classification of metallogenic units, these deposits belong to the Late Jurassic–Early Cretaceous Yana–Kolyma metallogenic belt. The Kyuchus deposit (~ 106 Ma), the Deputatsky ore cluster (~ 106–113 Ma), and the Khotoidokh deposit (~ 116 Ma) in the northern Verkhoyansk–Kolyma folded area belong to the North Verkhoyansk metallogenic belt. Their origin was associated with accretional and collisional processes that produced the Novosibirsk–Chukotka orogen in the middle Cretaceous. The Mangazeya ore cluster (~ 100 Ma, Early–Late Cretaceous boundary) in the southwestern end of the North Tirekhtyakh magmatic transverse belt belongs to the West Verkhoyansk metallogenic belt. The Nezhdaninskoe, Zaderzhnoe, Kurum, and Kuta deposits of the South Verkhoyansk area (~ 125–120 and ~ 100–95 Ma) can be joined into a single Verkhoyansk–Okhotsk metallogenic belt. The belt resulted from accretion and collision along the East Asian active continental margin and the related formation of the South Verkhoyansk orogen in the Early Cretaceous.