Isothermal growth of P-Si,N, crystals dispersed in an oxynitride glass (Y-Si-AI-0-N) was studied by electron microscopy after heat treatment at temperatures between 1550" and 1640°C for 1 to 18 h. The P-crystals exhibited growth striations introduced by intermediate coolings and these striations were used for developing a sophisticated technique for analysis of growth. It was determined that a/p-transformation and Ostwald ripening can be treated as different kinetic stages of grain growth, while p-nucleation was found to be insignificant. The mean diameter of the needlelike P-grains was almost constant during phase transformation, indicating negligible growth of the 9-prism plane; growth was mainly one-dimensional with the maximum mean length and aspect ratio just at the end of the phase transformation. The growth rate of the P-basal plane was independent of diameter, indicating interfacecontrolled growth. During Ostwald ripening, the length distribution broadened and the aspect ratio of smaller grains decreased. Dissolution of small grains caused an increase in the mean diameter, while the mean aspect ratio decreased.
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