The present study deals with the characterization of the polymeric materialsviz.,nylon-66 and 30% glass fibre reinforced nylon-66 (GF Nylon-66) by employing FTIR and thermal measurements. The complete vibrational band assignment made available for nylon-66 and GF nylon-66 using FTIR spectra confirm their chemical structure. FTIR spectroscopy provides detailed information on polymer structure through the characteristic vibrational energies of the various groups present in the molecule. The thermal behavior of nylon-66 and GF nylon-66 essential for proper processing and fabrication was studied from TGA and DTA thermograms. The thermal stability of the polymers was studied from TGA and the activation energy for the degradation of the polymeric materials was calculated using Murray-White plot and Coats-Redfern plot. The polymer with high activation energy is more thermally stable. GF nylon-66 is found to be more thermally stable than nylon-66. The major thermal transitions such as crystalline melting temperature (Tm) and degradation temperature (Td) of the polymers were detected from DTA curves. The melting behaviour of the polymer depends upon the specimen history and in particular upon the temperature of crystallization. The melting behaviour also depends upon the rate at which the specimen is heated. The various factors such as molar mass and degree of chain branching govern the value of Tmin different polymers.
Ferroelectric Potassium Dihydrogen Phosphate (KDP) crystals are widely used in modern short wavelength laser techniques, non-linear and integrated optics. The pure and -Histidine doped KDP crystals were procured from SRM Institute of Science and Technology, Chennai. The presence of additive in the doped KDP crystal is confirmed through X-Ray diffraction patterns and the lattice parameters were evaluated. Also, Fourier Transform Infrared spectrum confirms the presence of -Histidine in the doped crystals. The dielectric behaviour of the pure and doped crystals have been studied in the microwave region using K-band microwave bench equipped with the Gunn oscillator and guided with rectangular wave guide.
Effect of negatively charged dust on resistive instability corresponding to the electrostatic wave is investigated in a Hall thruster plasma when this purely azimuthal wave is tilted and strong axial component of wave vector is developed. Analytical calculations are done to obtain the relevant dispersion equation, which is solved numerically to investigate the growth rate of the instability. The magnitude of the growth rate in the plasma having dust particles is found to be much smaller than the case of pure plasma. However, the instability grows faster for the increasing dust density and the higher charge on the dust particles. The higher magnetic field is also found to support the instability.
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