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Three new quinoline and di‐tert‐butyl phenothiazine isomeric derivatives were synthesized and characterized towards applications for oxygen sensing and optical information multicoding. The compounds with phenylene linker showed outstanding phase‐dependent reversibility between ON/OFF states (low and high emission intensity, drastic shifting of emission colors, short‐ and long‐lived fluorescence) in systematic grinding/fuming cycles, as required for multichannel memory devices based on optical information multicoding. The conformational diversity of the phenothiazine unit resulted in dual emission of the doped films implemented by the different luminescence mechanisms with peaks located at 414/530, 416/540, and 440/582 nm. The presence of a phenylene linker and thus two rotational degrees of freedom resulted in quenching of the delayed fluorescence of quasi‐equatorial conformers in the solid state. The compound containing no phenylene bridge was characterized by two different driving photoluminescence mechanisms of the doped films: short fluorescence of the quasi‐axial conformer and thermally activated delayed fluorescence of the quasi‐equatorial form. This compound showed oxygen sensitivity with a Stern–Volmer constant of 7.5×10−4 ppm−1.