The effect of added salt on the propulsion of Janus platinum-polystyrene colloids in hydrogen peroxide solution is studied experimentally. It is found that micromolar quantities of potassium and silver nitrate salts reduce the swimming velocity by similar amounts, while leading to significantly different effects on the overall rate of catalytic breakdown of hydrogen peroxide. It is argued that the seemingly paradoxical experimental observations could be theoretically explained by using a generalised reaction scheme that involves charged intermediates and has the topology of two nested loops.
In this paper we show that processes such as Brownian motion, convection, sedimentation, and bacterial contamination can cause small particles to move through liquids in a fashion which may be mistaken as nanopropulsion. It is shown that particle tracking and subsequent statistical analysis is essential to ascertain if small particles actually propel themselves, or if they are propelled by another process. Specifically we find that it is necessary to calculate the mean-squared displacement of particles at both short and long time intervals, to show that the direction of propulsion changes coincident with rotation of the particle by Brownian motion, as this allows nanopropulsion to be differentiated from Brownian motion, convection and sedimentation. We also find that bacteria can attach themselves to particles and cause them to be propelled. This leads to motion which appears very similar to nanopropulsion and cannot be differentiated using particle tracking and therefore find that carefully designed control experiments must be performed. Finally, we suggest an experimental protocol which can be used to investigate the motion of small objects and prove if they move due to nanopropulsion.
“Self-lubricating organogels (SLUGs)”showing exceptional surface properties are preparedviaa crosslinking of polydimethylsiloxanes in the presence of organic liquids.
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