Electromagnetic (EM) absorbers play an increasingly essential role in the electronic information age, even toward the coming “intelligent era”. The remarkable merits of heterointerface engineering and its peculiar EM characteristics inject a fresh and infinite vitality for designing high‐efficiency and stimuli‐responsive EM absorbers. However, there still exist huge challenges in understanding and reinforcing these interface effects from the micro and macro perspectives. Herein, EM response mechanisms of interfacial effects are dissected in depth, and with a focus on advanced characterization as well as theoretical techniques. Then, the representative optimization strategies are systematically discussed with emphasis on component selection and structural design. More importantly, the most cutting‐edge smart EM functional devices based on heterointerface engineering are reported. Finally, current challenges and concrete suggestions are proposed, and future perspectives on this promising field are also predicted.

Highlights The eco-friendly shaddock peel-derived carbon aerogels were prepared by a freeze-drying method. Multiple functions such as thermal insulation, compression resistance and microwave absorption can be integrated into one material-carbon aerogel. Novel computer simulation technology strategy was selected to simulate significant radar cross-sectional reduction values under real far field condition. . Abstract Eco-friendly electromagnetic wave absorbing materials with excellent thermal infrared stealth property, heat-insulating ability and compression resistance are highly attractive in practical applications. Meeting the aforesaid requirements simultaneously is a formidable challenge. Herein, ultra-light carbon aerogels were fabricated via fresh shaddock peel by facile freeze-drying method and calcination process, forming porous network architecture. With the heating platform temperature of 70 °C, the upper surface temperatures of the as-prepared carbon aerogel present a slow upward trend. The color of the sample surface in thermal infrared images is similar to that of the surroundings. With the maximum compressive stress of 2.435 kPa, the carbon aerogels can provide favorable endurance. The shaddock peel-based carbon aerogels possess the minimum reflection loss value (RLmin) of − 29.50 dB in X band. Meanwhile, the effective absorption bandwidth covers 5.80 GHz at a relatively thin thickness of only 1.7 mm. With the detection theta of 0°, the maximum radar cross-sectional (RCS) reduction values of 16.28 dB m2 can be achieved. Theoretical simulations of RCS have aroused extensive interest owing to their ingenious design and time-saving feature. This work paves the way for preparing multi-functional microwave absorbers derived from biomass raw materials under the guidance of RCS simulations.

With the continuous deterioration of the electromagnetic environment, there is an urgent need for exploring highly efficient and widely applicable electromagnetic interference shielding and microwave absorption materials. In current years,...

Because of their unique three-dimensional cellular structure and intrinsic properties, polyimide foam materials have bright prospects for development in multiple functional equipment, which arouses extensive concern. In this Spotlight on Applications, several typical fabrication methods of polyimide foams and the related synthesis mechanism have been systematically described. The advantages and disadvantages of the preparation methods have been compared with each other. Representative functions and the corresponding mechanism models have been concluded, which involve thermal, mechanical, sensing, electromagnetic, environmental, and electrical fields. In the end, the severe tasks and challenges of polyimide foam materials have been summarized, and their promising future development is worth expecting.

Silver nanowire (Ag NW) has been considered as the promising building block for the fabrication of transparent electromagnetic interference (EMI) shielding films. However, the practical application of Ag NW-based EMI shielding films has been restricted due to the unsatisfactory stability of Ag NW. Herein, we proposed a reduced graphene oxide (rGO) decorated Ag NW film, which realizes a seamless integration of optical transparency, highly efficient EMI shielding, reliable durability and stability. The Ag NW constructs a highly transparent and conductive network, and the rGO provides additional conductive path, showing a superior EMI shielding effectiveness (SE) of 33.62 dB at transmittance of 81.9%. In addition, the top rGO layer enables the hybrid film with reliable durability and chemical stability, which can maintain 96% and 90% EMI SE after 1000 times bending cycles at radius of 2 mm and exposure in air for 80 days. Furthermore, the rGO/Ag NW films also possess fast thermal response and heating stability, making them highly applicable in wearable devices. The synergy of Ag NW and rGO grants the hybrid EMI shielding film multiple desired functions and meanwhile overcomes the shortcomings of Ag NW. This work provides a reference for preparing multifunctional integrated transparent EMI shielding film.