The experimental studies were conducted to estimate the effect of surfactant additives on the volume and the pressure of the CO2 gas generated according to the new proposed technology. An experimental device was designed and built specifically for these purposes. The designed setup allowed initiating and controlling the reaction between the "gas-yielding" (GY) and "gas-forming" (GF) agents proposed by this technology. The temperature was controlled, and the generated gas pressure and volume were recorded during the reaction process. Three types of surfactants were tested to estimate the effect on volume and pressure of generated CO2 gas. The preliminary experimental results on CO2 gas pressure measurements demonstrated that the gas pressure increases withsurfactant addition,decreasing the temperature, andincreasing salinity of the system. INTRODUCTION Dense phase gases (carbon dioxide, nitrogen, light hydrocarbons, etc.) are used to develop miscibility with crude oil in enhanced oil recovery processes. Due to the following reasons, carbon dioxide (CO2) flooding is considered the fastest-growing improved oil recovery method [1]: However, due to the low viscosity of dense CO2 (up to 20% of viscosity of oil), displacement front instabilities and a premature CO2 breakthrough is observed in many cases. In order to control the mobility of CO2 flooding, the gas injection is alternated with surfactant solution [1], which results in generation of foam (colloidal dispersion of gas in liquid). A thin intermediate boundary between the dispersed and continuous phases is called interface. The region that covers the thin film with two interfaces on its each side is called lamella. Each lamella has a link to other lamellae.

Dense phase gases (carbon dioxide, nitrogen, light hydrocarbons, etc.) are used to develop miscibility with crude oil in enhanced oil recovery processes. Due to the certain reasons, carbon dioxide (CO2) flooding is considered the fastest-growing improved oil recovery method. However, due to the low viscosity of dense CO2, displacement front instabilities and a premature CO2 breakthrough is observed in many cases. An alternative scheme to the traditional methods of oil recovery by injection of carbon dioxide gas is the technology developed by the NMT, IGDFF and IMM, which proposes in-situ CO2 generation as a result of the thermochemical reaction between water solutions of the gas-forming (FG) and gas-yielding (GY) chemical agents injected to the productive horizons. This technique excludes CO2 injection from surface communication systems and does not require expensive delivery equipment. This process allows avoiding many negative consequences of CO2 injection technology. Based on the in-situ CO2 generation concept, several new technological schemes were developed in order to provide an integrative effect on the productive horizons. In this paper we present the results of the experimental studies on effect of polymer and surfactant additives on generated CO2 miscibility. The solutions of gas-yielding (GY) agent with different concentrations of surfactants and polymer additives were used as a reacting agent in these laboratory studies. Within the limits of the experimental conditions stochiometric reactions between gas-yielding (GY) and gas-forming (GF) water solutions were simulated. The tests were conducted on the experimental set up designed and built for these purposes. In the first series of experiments a polyacrylamide was added to the gas-yielding (GY) agent in the concentrations 0.1, 0.25 and 0.5 wt.%. A dynamics of the pressure changes during stoichiometric reaction was recorded. It is shown that the pressure of the generated CO2 gas significantly depends on concentration of the polymer additive and, as a consequence, on viscosity of the water solution. It slightly depends on the concentration of the surfactant added to the GY reactant.

The experimental studies were conducted to measure the volume and the pressure of the CO2 gas generated according to the new oil recovery technology. An experimental device was designed, built and used for these purposes. The designed setup allowed initiating and controlling the reaction between the “gas-yielding” (GY) and “gas-forming” (GF) agents proposed by this technology. The temperature was controlled, and the generated gas pressure and volume were recorded during the reaction process. The effect of water salinity on generated CO2 gas pressure and volume was investigated.

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Experimental simulation of chemical reaction behavior between gas-forming (GF) and carbonate rock components has been conducted. During the reaction an allocation of carbon dioxide and pressure change in PVT bombe were discovered. In these series of experiments a dynamics of pressure and temperature changes during stoichiometric reaction between GF reactant and a carbonate rock was investigated. The GY component was prepared on fresh water (Shollar). As a carbonate rock samples, Karadag rock deposits (Azerbaijan) were used. Researches were conducted at constant temperature T=293 K and at various volumetric ratios of GY reactant and a carbonate rock The quantity of reacting agents was defined from stoichiometric correlation which provided a full neutralization of the tested rock.