Gas flow behavior in porous media with micro- and nanoscale pores has always been attracted great attention. Gas transport mechanism in such pores is a complex problem, which includes continuous flow, slip flow and transition flow. In this study, the microtubes of quartz microcapillary and nanopores alumina membrane were used, and the gas flow measurements through the microtubes and nanopores with the diameters ranging from 6.42 μm to 12.5 nm were conducted. The experimental results show that the gas flow characteristics are in rough agreement with the Hagen-Poiseuille (H-P) equation in microscale. However, the flux of gas flow through the nanopores is larger than the H-P equation by more than an order of magnitude, and thus the H-P equation considerably underestimates gas flux. The Knudsen diffusion and slip flow coexist in the nanoscale pores and their contributions to the gas flux increase as the diameter decreases. The slip flow increases with the decrease in diameter, and the slip length decreases with the increase in driving pressure. Furthermore, the experimental gas flow resistance is less than the theoretical value in the nanopores and the flow resistance decreases along with the decrease in diameter, which explains the phenomenon of flux increase and the occurrence of a considerable slip length in nanoscale. These results can provide insights into a better understanding of gas flow in micro- and nanoscale pores and enable us to exactly predict and actively control gas slip.

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Janus nanoparticles have aroused the interest of scholars because of their highly efficient emulsification of spilled oils in wastewater. In this work, interfacially active Janus hollow glass microparticles (J-HGMPs) of asymmetric wettability were designed and synthesized in order to achieve more efficient separation of emulsified oil droplets from oily wastewater. Surface characteristic techniques such as FTIR, SEM, zeta potential and contact angle measurements had been employed to assess the amphiphilic surface properties of J-HGMPs. The oil removal/recovery performance of J-HGMPs in different oil–water systems and their interfacial activities were studied. As a particulate emulsifier, J-HGMPs could remove/recover > 96% oil from oil–water mixed phase. The results showed that J-HGMPs had strong interfacial activities and anchored firmly at oil/water interfaces. This high adsorption energy was also evaluated and verified via the calculation of Gibbs free energy. Overall, this study provided a novel and low-cost oil recovery method via a convenient buoyancy force that could be effectively applied in the treatment of oil spills while achieving the goal of benign and green environmental protection.

In the actual production and operation of enterprises, it is sometimes inevitable that the floating roof will fall to the bottom. This paper calculates the explosion limit of the mixture of oil gas under the floating roof, and confirms that the concentration of oil gas will be within the explosion limit under certain circumstances. Through the monitoring and analysis of the oil-gas mixing space below the floating roof, corresponding control measures are proposed to deal with the potential safety hazards of the floating plate falling to the bottom.

This paper classifies more than 20 accidents according to the main factors and types of accidents from 1994 to now. Through analysis, it is found that the safety attachment of LNG pressure control is a weak link in LNG storage system. The safety attachment of LNG pressure control is analyzed from four aspects of people machine Environmental management, and the fault tree model is established. After calculation, the minimum cut set and structural importance of the safety attachment of LNG pressure control are obtained. Based on the fault tree analysis results of LNG pressure control safety accessories and the statistical results of 20 accidents, control measures and suggestions are put forward from the peripheral layout, electrical, equipment, installation, production operation, daily maintenance of LNG pressure control safety accessories, in order to prevent and reduce accidents caused by LNG pressure control safety accessories.