A wave dynamics of fields φ(p, q; t) ∈ L2(Γ) over the phase space Γ(p, q) of a classical system 𝒮 is derived from the Liouville theorem. We define the energy contained in a given field φ(p, q; t). We show that for a special class of fields, selected on physical grounds, the energy spectrum is given by a time-independent Schrödinger equation. This allows us to associate with 𝒮 an ordinary quantum system Q such that the values of the quantized energy coincide for the fields in the phase space of 𝒮 and for Q. Then we make use of Wiener's stochastic integral based on the theory of Brownian motion to derive probabilities which are the same as those one would obtain through Born's statistical postulate of quantum theory. From this it follows that we can regard normalized fields φ(p, q; t) as ``probability amplitudes'' leading to a probability density function ρ(p, q; t) = φφ* in the sense of Gibbs' statistical mechanics. Our work therefore appears as a bridge between a statistical theory (in the sense of Gibbs) of a mechanical system 𝒮 and the usual quantum theory of the related quantum system Q.
The electron network model of Coulson and Della Riccia is applied to describe a simple lattice consisting of two families of linear chains, coupled together. It is shown that the model displays resonances, at which the wavefunction is preferentially situated at one or the other family of chains, and that at these resonances, there is a 1/√E divergence in the electronic density of states.
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