We report an entirely new class of printed electrical gas sensors that are produced at near "zero cost". This technology exploits the intrinsic hygroscopic properties of cellulose fibers within paper; although it feels and looks dry, paper contains substantial amount of moisture, adsorbed from the environment, enabling the use of wet chemical methods for sensing without manually adding water to the substrate. The sensors exhibit high sensitivity to water-soluble gases (e.g., lower limit of detection for NH 3 < 200 parts-per-billion) with a fast and reversible response. The sensors show comparable or better performance (especially at high relative humidity) than most commercial ammonia sensors at a fraction of their price (<$0.02 per sensor). We demonstrate that the sensors proposed can be integrated into food packaging to monitor freshness (to reduce food waste and plastic pollution) or implemented into near-field-communication tags to function as wireless, battery-less gas sensors that can be interrogated with smartphones.

With the emergence of stretchable/wearable devices, functions, such as sensing, energy storage/harvesting, electrical conduction, should ideally be carried out by a single material, while retaining its mechanical properties (e.g. ability...

Commercially available metal inks are mainly designed for planar substrates (for example, polyethylene terephthalate foils or ceramics), and they contain hydrophobic polymer binders that fill the pores in fabrics when printed, thus resulting in hydrophobic electrodes. Here, a low-cost binder-free method for the metallization of woven and nonwoven fabrics is presented that preserves the 3D structure and hydrophilicity of the substrate. Metals such as Au, Ag, and Pt are grown autocatalytically, using metal salts, inside the fibrous network of fabrics at room temperature in a two-step process, with a water-based silicon particle ink acting as precursor. Using this method, (patterned) metallized fabrics are being enabled to be produced with low electrical resistance (less than 3.5 Ω sq −1 ). In addition to fabrics, the method is also compatible with other 3D hydrophilic substrates such as nitrocellulose membranes. The versatility of this method is demonstrated by producing coil antennas for wireless energy harvesting, Ag-Zn batteries for energy storage, electrochemical biosensors for the detection of DNA/proteins, and as a substrate for optical sensing by surface enhanced Raman spectroscopy. In the future, this method of metallization may pave the way for new classes of high-performance devices using low-cost fabrics.

No abstract

Printed electrical gas sensors are a low-cost, lightweight, low-power, and potentially disposable alternative to gas sensors manufactured using conventional methods such as photolithography, etching, and chemical vapor deposition. The growing interest in Internet-of-Things, smart homes, wearable devices, and point-of-need sensors has been the main driver fueling the development of new classes of printed electrical gas sensors. In this Perspective, we provide an insight into the current research related to printed electrical gas sensors including materials, methods of fabrication, and applications in monitoring food quality, air quality, diagnosis of diseases, and detection of hazardous gases. We further describe the challenges and future opportunities for this emerging technology.