We analyse the dynamics of a two dimensional system of interacting active dumbbells. We characterise the mean-square displacement, linear response function and deviation from the equilibrium fluctuation-dissipation theorem as a function of activity strength, packing fraction and temperature for parameters such that the system is in its homogeneous phase. While the diffusion constant in the last diffusive regime naturally increases with activity and decreases with packing fraction, we exhibit an intriguing non-monotonic dependence on the activity of the ratio between the finite density and the single particle diffusion constants. At fixed packing fraction, the time-integrated linear response function depends non-monotonically on activity strength. The effective temperature extracted from the ratio between the integrated linear response and the mean-square displacement in the last diffusive regime is always higher than the ambient temperature, increases with increasing activity and, for small active force it monotonically increases with density while for sufficiently high activity it first increases to next decrease with the packing fraction. We ascribe this peculiar effect to the existence of finite-size clusters for sufficiently high activity and density at the fixed (low) temperatures at which we worked. The crossover occurs at lower activity or density the lower the external temperature. The finite density effective temperature is higher (lower) than the single dumbbell one below (above) a cross-over value of the Péclet number.

Detlef (2016) Collective and convective effects compete in patterns of dissolving surface droplets. Soft Matter, 12 (26 Northumbria University has developed Northumbria Research Link (NRL) to enable users to access the University's research output. Copyright © and moral rights for items on NRL are retained by the individual author(s) and/or other copyright owners. Single copies of full items can be reproduced, displayed or performed, and given to third parties in any format or medium for personal research or study, educational, or not-for-profit purposes without prior permission or charge, provided the authors, title and full bibliographic details are given, as well as a hyperlink and/or URL to the original metadata page. The content must not be changed in any way. Full items must not be sold commercially in any format or medium without formal permission of the copyright holder. The full policy is available online: http://nrl.northumbria.ac.uk/policies.html This document may differ from the final, published version of the research and has been made available online in accordance with publisher policies. To read and/or cite from the published version of the research, please visit the publisher's website (a subscription may be required.) This is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication.Accepted Manuscripts are published online shortly after acceptance, before technical editing, formatting and proof reading. Using this free service, authors can make their results available to the community, in citable form, before we publish the edited article. We will replace this Accepted Manuscript with the edited and formatted Advance Article as soon as it is available.You can find more information about Accepted Manuscripts in the Information for Authors. The effect of neighboring droplets on the dissolution of a sessile droplet, i.e. collective effects, are investigated both experimentally and numerically. On the experimental side small 20 n approximately mono-disperse surface droplets arranged in an ordered pattern were dissolved and their size evolution is studied optically. The droplet dissolution time was studied for various droplet patterns. On the numerical side, Lattice-Boltzmann simulations were performed. Both simulations and experiments show that the dissolution time of a droplet placed in the center of a pattern can increase with as much as 60% as compared to a single, isolated droplet, due to the shielding effect of the neighboring droplets. However, the experiments also show that neighboring droplets enhance the buoyancy driven convective flow of the bulk, increasing the mass exchange and counteracting collective effects. We show that this enhanced convection can reduce the dissolution time of droplets at the edges of the pattern to values below that of a single, isolated droplet.

The instabilities of fluid interfaces represent both a limitation and an opportunity for the fabrication of small-scale devices. Just as non-uniform capillary pressures can destroy micro-electrical mechanical systems (MEMS), so they can guide the assembly of novel solid and fluid structures. In many such applications the interface appears during an evaporation process and is therefore only present temporarily. It is commonly assumed that this evaporation simply guides the interface through a sequence of equilibrium configurations, and that the rate of evaporation only sets the timescale of this sequence. Here, we use Lattice-Boltzmann simulations and a theoretical analysis to show that, in fact, the rate of evaporation can be a factor in determining the onset and form of dynamical capillary instabilities. Our results shed light on the role of evaporation in previous experiments, and open the possibility of exploiting diffusive mass transfer to directly control capillary flows in MEMS applications.