Abstract. The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), on-board the European ENVIronmental SATellite (ENVISAT) launched on 1 March 2002, is a middle infrared Fourier Transform spectrometer measuring the atmospheric emission spectrum in limb sounding geometry. The instrument is capable to retrieve the vertical distribution of temperature and trace gases, aiming at the study of climate and atmospheric chemistry and dynamics, and at applications to data assimilation and weather forecasting.Correspondence to: U. Cortesi (u.cortesi@ifac.cnr.it) MIPAS operated in its standard observation mode for approximately two years, from July 2002 to March 2004, with scans performed at nominal spectral resolution of 0.025 cm −1 and covering the altitude range from the mesosphere to the upper troposphere with relatively high vertical resolution (about 3 km in the stratosphere). Only reduced spectral resolution measurements have been performed subsequently. MIPAS data were re-processed by ESA using updated versions of the Instrument Processing Facility (IPF v4.61 and v4.62) (and, to a lesser extent, v4.62) O 3 VMR profiles and a comprehensive set of correlative data, including observations from ozone sondes, ground-based lidar, FTIR and microwave radiometers, remote-sensing and in situ instruments on-board stratospheric aircraft and balloons, concurrent satellite sensors and ozone fields assimilated by the European Center for Medium-range Weather Forecasting.A coordinated effort was carried out, using common criteria for the selection of individual validation data sets, and similar methods for the comparisons. This enabled merging the individual results from a variety of independent reference measurements of proven quality (i.e. well characterized error budget) into an overall evaluation of MIPAS O 3 data quality, having both statistical strength and the widest spatial and temporal coverage. Collocated measurements from ozone sondes and ground-based lidar and microwave radiometers of the Network for the Detection Atmospheric Composition Change (NDACC) were selected to carry out comparisons with time series of MIPAS O 3 partial columns and to identify groups of stations and time periods with a uniform pattern of ozone differences, that were subsequently used for a vertically resolved statistical analysis. The results of the comparison are classified according to synoptic and regional systems and to altitude intervals, showing a generally good agreement within the comparison error bars in the upper and middle stratosphere. Significant differences emerge in the lower stratosphere and are only partly explained by the larger contributions of horizontal and vertical smoothing differences and of collocation errors to the total uncertainty. Further results obtained from a purely statistical analysis of the same data set from NDACC ground-based lidar stations, as well as from additional ozone soundings at middle latitudes and from NDACC ground-based FTIR measurements, confirm the validity of MIPAS O 3 profil...

We report the most accurate measurement of the helium fine structure splitting. The 2 3 P 0 -2 3 P 1 energy splitting is 29 616 949.7 6 2.0 kHz. Laser saturation spectroscopy, heterodyne pure frequency determination, and fluorescence detection were combined in a novel experimental approach. The absence of external perturbing magnetic fields, used in earlier experiments, lends confidence to our determined value and allows us to discriminate between contradictory results previously reported. This result, when combined with expected advances in theory, should yield a new value of the fine structure a, which may help clarify a presently puzzling experimental situation. [S0031-9007(99)08416-1]

Abstract. The ENVISAT validation programme for the atmospheric instruments MIPAS, SCIAMACHY and GOMOS is based on a number of balloon-borne, aircraft, satellite and ground-based correlative measurements. In particular the activities of validation scientists were coordinated by ESA within the ENVISAT Stratospheric Aircraft and Balloon Campaign or ESABC. As part of a series of similar papers on other species [this issue] and in parallel to the contribution of the individual validation teams, the present paper provides a synthesis of comparisons performed between MIPAS CH 4 and N 2 O profiles produced by the current ESA operational software (Instrument Processing Facility version

Water vapor and clouds are among the most important greenhouse components whose radiative features cover all the broad spectral range of the thermal emission of the atmosphere. Typically more than 40% of the total thermal emission of Earth occurs in the far-infrared (FIR) spectral region from 100 to 667 cm−1 (wavelengths from 100 to 15 µm). Nevertheless, this spectral region has not ever been fully covered down to 100 cm−1 by space missions, and only a few ground-based experiments exist because of the difficulty of performing measurements from high altitude and very dry locations where the atmosphere is sufficiently transparent to observe the FIR emission features. To cover this lack of observations, the Italian experiment “Radiative Properties of Water Vapor and Clouds in Antarctica” has collected a 2-yr dataset of spectral measurements of the radiance emitted by the atmosphere and by clouds, such as cirrus and polar stratospheric clouds, from 100 to 1,400 cm−1 (100–7 µm of wavelength), including the underexplored FIR region, along with polarization-sensitive lidar observations, daily radiosondes, and other ancillary information to characterize the atmosphere above the site. Measurements have been performed almost continuously with a duty cycle of 6 out of 9 h, from the Italian–French base of Concordia at Dome C over the Antarctic Plateau at 3,230 m MSL, in all-sky conditions since 2012. Because of the uniqueness of the observations, this dataset will be extremely valuable for evaluating the accuracy of atmospheric absorption models (both gas and clouds) in the underexplored FIR and to detect possible daily, seasonal, and annual climate signatures.

The paper presents a novel methodology to retrieve the foreign-broadened water vapor continuum absorption coefficients in the spectral range 240 to 590 cm(-1) and is the first estimation of the continuum coefficient at wave numbers smaller than 400 cm(-1) under atmospheric conditions. The derivation has been accomplished by processing a suitable set of atmospheric emitted spectral radiance observations obtained during the March 2007 Alps campaign of the ECOWAR project (Earth Cooling by WAter vapor Radiation). It is shown that, in the range 450 to 600 cm(-1), our findings are in good agreement with the widely used Mlawer, Tobin-Clough, Kneizys-Davies (MT CKD) continuum. Below 450 cm(-1) however the MT CKD model overestimates the magnitude of the continuum coefficient.