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Heat exchangers are used in gas burners as recuperators. Their efficiency is proportional to their surface which is usually limited by the burner length and diameter. Ceramic recuperators used nowadays in industrial burners are tubular. We studied and developed a new generation of ceramic heat exchanger with the final goal of increasing the efficiency or, at similar efficiencies, of reducing their size and weight. A commercial SiSiC heat exchanger component was used to guarantee safety and robustness. The use of structured textile geometries followed by their conversion into a ceramic is the main innovation of this work.

Si–SiC–ZrB2 are produced by the reactive infiltration with molten silicon in porous SiC–C–ZrB2 preforms. It is observed that oxidized Si–SiC–ZrB2 ceramics present a layered structure composed of an outer layer of silica and a borosilicate glass intermediate layer with ZrO2 particles and the unoxidized bulk material. The graphs show that the passivation is very effective already after 5 min of oxidation. The thermograms do not vary significantly when the oxidation times are increased.

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