A novel versatile electrical skin (e-skin) with safeguarding and multisensing properties based on hybrid structures is developed by assembling Ag nanowires (AgNWs), polyester (PET) film with hybrid shear stiffening polymer/polydimethylsiloxane (SST/PDMS) matrix. The hybrid SST/PDMS polymer shows stable configuration. Storage modulus of the SST/PDMS increases from 5.5 kPa to 0.39 MPa when the shear frequency changes from 0.1 to 100 Hz, exhibiting typical rate-dependent behavior. e-Skin functions as a human-monitoring device by detecting various motions such as gentle touching, stroking, elbow bending, as well as speaking. More importantly, due to the shear stiffening characteristic, e-skin with high damping capacity exhibits safeguarding performance, which can dissipate impact force from 720 to 400 N and increase buffer time (from 0.9 to 2 ms). Meanwhile, distinguishable resistance values can reveal the level of harsh impact applied on the e-skin. In addition, the visible thermosensation effect of e-skin similar to chameleon epidermis is convenient for assessing environmental temperature. e-Skin arrays can precisely map the dynamic impact location and pressure distribution. Finally, the high electrical sensitivity and shear stiffening performance are attributed to the disturbance of AgNW effective conductive paths and dynamic BO bonds, respectively.

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