One-dimensional Fe, Co, Ni nanotube arrays ware fabricated successfully by the electrochemical deposit in porous anodic alumina oxide (AAO) templates. The microstructure of nanotubes were observed by scanning (SEM) and transmission electron microscopes (TEM) respectively. The obtained Fe, Co, Ni nanotubes are arranged orderly. The magnetic property of nanotubes was measured and analyzed. The results show that the residual magnetization of Ni nanotubes is the biggest, and that of Fe nanotubes is the smallest. It is easy to be magnetized along the axial direction.
By mechanical blending method or melt extrusion method, several kinds of poymers and OMMT were selected with different mixing progress and conditions, and several polymer/OMMT nanocomposites with different substructure morphology were prepared. The properties of polymer/OMMT nanocomposites were investigated. Firstly, several types of OMMT were prepared with different layer spacing, the results of XRD and TEM showed that the OMMT with larger layer spacing would form exfoliation nanocomposites, and then the schemes explained the mechanism. The polyethylene (such as LDPE, HDPE, LLDPE) composited with the same OMMT indicated the influence of different molecular chain structure. Different morphology of PP/OMMT and EPDM/OMMT nano-composites were discussed to find the relationship of shear force effecting structure.
The cis-1,4-polybutadiene rubber(BR)/organic montmorillonite(OMMT) /attpulgite(AT) nanocomposites were prepared by using solution method. The results of TEM showed that the OMMT and AT layers were dispersed in BR matrix on nano-scale. Compared with the pure BR, the tensile strength of BR/OMMT/AT nanocomposites increased by 600% when added 6% OMMT/AT. The results showed that the conversion of butadiene polymerization was higher than 90% by using recycled solvent. The nanocomposites had excellent thermal stability. The dynamic mechanical analysis showed that Tg of BR/OMMT/AT nanocomposites shifted to higher temperature, and the nanocomposites had a good rolling resistance. The composites displayed better dynamic mechanical properties.
Trilateral Flash Cycle (TFC) is particularly suitable for recovering energy from low-grade heat source. This paper presented a new mathematical model for calculating the performance of a twin screw expander integrated into a TFC working with organic components. The geometric parameters related to the rotation angle of male rotor e.g. groove volume, suction and discharge port area, leakage area etc were used in the model. The combination effects of internal leakage through five paths, oil injection, gas-oil heat transfer and refrigerant property were taken into account. The sensitivity of single parameter was also analyzed. To verify the model and the calculated p-φ indicator diagram, experimental recording of the diagram of twin screw expander was performed. The results of theoretical calculation were in good agreement with the experimental data, which indicated that the model in the present paper could be used as a powerful tool for performance prediction and product development.
The CR/OMMT nanocomposites were prepared by mechanical blending, and the microstructure and properties of nanocomposites were studied. The half-exfoliated organoclay nanocomposites with uniform dispersion were confirmed by transmission electron microscopy (TEM) and X-ray diffraction (XRD), and the cure characteristic, physics mechanical and anti-aging properties of CR/OMMT nanocomposites due to the percent of OMMT were discussed. The results showed that the tear strength and the tensile strength of the nanocomposites with 5 phr OMMT were improved by 49% and 53.3%, respectively. The anti-aging properties of nanocomposites were improved greatly. OMMT could participate in the vulcanization reaction, reduced the cure time (T90) of nanocomposites, and raised the production efficiency.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.