Antibacterial
air filtration membranes are essential for personal
protection during the pandemic of coronavirus disease 2019 (COVID-19).
However, high-efficiency filtration with low pressure drop and effective
antibiosis is difficult to achieve. To solve this problem, an innovative
electrospinning system with low binding energy and high conductivity
was built to enhance the jet splitting, and a fluffy nanofibrous membrane
containing numerous ultrafine nanofibers and large quantities of antibacterial
agents was achieved, which was fabricated by electrospinning polyamide
6 (PA6), poly(vinyl pyrrolidone) (PVP), chitosan (CS), and curcumin
(Cur). The filtration efficiency for 0.3 μm NaCl particles was
99.83%, the pressure drop was 54 Pa, and the quality factor (QF) was
up to 0.118 Pa–1. CS and Cur synergistically enhanced
the antibacterial performance; the bacteriostatic rates against Escherichia coli and Staphylococcus
aureus were 99.5 and 98.9%, respectively. This work
will largely promote the application of natural antibacterial agents
in the development of high-efficiency, low-resistance air filters
for personal protection by manufacturing ultrafine nanofibers with
enhanced antibiosis.
The stable and continuous ejection of multiple jets with high densities is the key to the application of electrospinning technology. An arced multi-nozzle spinneret was designed to increase the production efficiency of electrospinning. The distribution of the electrical field was simulated to optimize the nozzles’ distribution of the spinneret. When the nozzles were arranged in an arc array, a relatively uniform electrical field could be obtained, which was beneficial for the weakening of electrical interference among the nozzles. Under the optimized electrical field, multiple jets from each nozzle could be ejected in a stable and continuous way. With the increase of the applied voltage, the electrical stretching force became larger, and there were fewer bonding structures. The average diameter of the electrospun nanofibers decreased with the increase of the applied voltage. When the distance between the inner nozzle and the collector increased, the charged jets suffered a larger stretching effect, resulting in the decrease of the average diameter of the electrospun nanofibers. The electrospinning current increased with the applied voltage and decreased with the distance between the inner nozzle and the collector, which is an important aspect for the monitoring of electrospinning jets. This work provides an effective way to promote the production efficiency of electrospun nanofibrous membranes.
Stability control of electrohydrodynamic (EHD) printing technology is urgent needed for efficient fabrication of flexible electronics. In this study, a new fast on–off controlling technology for micro droplets of EHD is proposed by applying an AC induced voltage. The suspending droplet interface is broken through quickly, and the impulse current can be significantly reduced from 527.2 to 50.14 nA, which greatly reduces its negative impact on jet stability. What’s more, time interval of jet generation can be shortened by a factor of three, while not only significantly improving the uniformity of the droplets, but effectively reducing the droplet size from 195 to 104 μm. Moreover, the controllable and mass formation of micro droplets are realized, but also the structure of each droplet is able to be controlled independently, which promoted the development of EHD printing technology in more fields.
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