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For tp-scan experiments rotating the crystal through a three-beam case the rocking-curve: profiles have been calculated on the basis of the dynamical theory of X-ray diffraction. Divergence and wavelength spread of the incident beam have been taken into account. It is shown that for centrosymmetric crystal structures the asymmetry of the profiles is related to the sign of the triple product of the structure factorswhich are involved in a three-beam case. If anomalous absorption ('double Borrmann' effect) can be neglected the typical asymmetry is independent of the diffraction geometry (Laue or Bragg case). For Laue geometry and thick crystals Co t > 1) corrections are necessary. For centrosymmetric structures it may be possible to determine the phase sum of a triplet by inspection of the rocking curve without computer calculations. The general features of the rocking curve are discussed and a physical interpretation is given.

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