Context. The globular cluster HP 1 is projected at only 3 • .33 from the Galactic center. Together with its distance, this makes it one of the most central globular clusters in the Milky Way. It has a blue horizontal branch (BHB) and a metallicity of [Fe/H] ≈ −1.0. This means that it probably is one of the oldest objects in the Galaxy. Abundance ratios can reveal the nucleosynthesis pattern of the first stars as well as the early chemical enrichment and early formation of stellar populations. Aims. High-resolution spectra obtained for six stars were analyzed to derive the abundances of the light elements C, N, O, Na, and Al, the alpha-elements Mg, Si, Ca, and Ti, and the heavy elements Sr, Y, Zr, Ba, La, and Eu. Methods. High-resolution spectra of six red giants that are confirmed members of the bulge globular cluster HP 1 were obtained with the 8 m VLT UT2-Kueyen telescope with the UVES spectrograph in FLAMES-UVES configuration. The spectroscopic parameter derivation was based on the excitation and ionization equilibrium of Fe i and Fe ii.

Aims. Globular clusters are tracers of the history of star formation and chemical enrichment in the early Galaxy. Their abundance pattern can help understanding their chemical enrichment processes. In particular, the iron-peak elements have been relatively little studied so far in the Galactic bulge. Methods. The main aim of this work is to verify the strength of abundances of iron-peak elements for chemical tagging in view of identifying different stellar populations. Besides, the nucleosynthesis processes that build these elements are complex, therefore observational data can help constraining theoretical models, as well as give hints on the kinds of supernovae that enriched the gas before these stars formed.Results. The abundances of iron-peak elements are derived for the sample clusters, and compared with bulge field, and thick disk stars. We derive abundances of the iron-peak elements Sc, V, Mn, Cu, and Zn in individual stars of five bulge globular clusters (NGC 6528, NGC 6553, NGC 6522, NGC 6558, HP 1), and of the reference thick disk/inner halo cluster 47 Tucanae (NGC 104). High resolution spectra were obtained with the UVES spectrograph at the Very Large Telescope over the years.Conclusions. The sample globular clusters studied span metallicities in the range -1.2 < ∼ [Fe/H] < ∼ 0.0. V and Sc appear to vary in lockstep with Fe, indicating that they are produced in the same supernovae as Fe. We find that Mn is deficient in metal-poor stars, confirming that it is underproduced in massive stars; Mn-over-Fe steadily increases at the higher metallicities due to a metallicity-dependent enrichment by supernovae of type Ia. Cu behaves as a secondary element, indicating its production in a weak-s process in massive stars. Zn has an alpha-like behaviour at low metallicities, which can be explained in terms of nucleosynthesis in hypernovae. At the metal-rich end, Zn decreases with increasing metallicity, similarly to the alpha-elements.

Context. NGC 6558 is a bulge globular cluster with a blue horizontal branch (BHB), combined with a metallicity of [Fe/H]≈-1.0. It is similar to HP 1 and NGC 6522, which could be among the oldest objects in the Galaxy. Element abundances in these clusters could reveal the nature of the first supernovae. Aims. We aim to carry out detailed spectroscopic analysis for four red giants of NGC 6558, in order to derive the abundances of the light elements C, N, O, Na, Al, the α-elements Mg, Si, Ca, Ti, and the heavy elements Y, Ba, and Eu. Methods. High-resolution spectra of four stars with FLAMES-UVES@VLT UT2-Kueyen were analysed. Spectroscopic parameter-derivation was based on excitation and ionization equilibrium of Fe I and Fe II.Results. This analysis results in a metallicity of [Fe/H] = −1.17 ± 0.10 for NGC 6558. We find the expected α-element enhancements in O and Mg with [O/Fe]=+0.40, [Mg/Fe]=+0.33, and low enhancements in Si and Ca. Ti has a moderate enhancement of [Ti/Fe]=+0.22. The r-element Eu appears very enhanced with a mean value of [Eu/Fe]=+0.63. Ba appears to have a solar abundance ratio relative to Fe. Conclusions. NGC 6558 shows an abundance pattern that could be typical of the oldest inner bulge globular clusters, together with the pattern in the similar clusters NGC 6522 and HP 1. They show low abundances of the odd-Z elements Na and Al, and of the explosive nucleosynthesis α-elements Si, Ca, and Ti. The hydrostatic burning α-elements O and Mg are normally enhanced as expected in old stars enriched with yields from core-collapse supernovae, and the iron-peak elements Mn, Cu, Zn show low abundances, which is expected for Mn and Cu, but not for Zn. Finally, the cluster trio NGC 6558, NGC 6522, and HP 1 show similar abundance patterns.