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This letter reports a giant magnetocaloric effect (GMCE) in a novel series of materials based on the shape memory alloy Ni 2 MnGa. The origin of an enhanced GMCE is traced to the coincidence of a first-order magnetic transition and its attendant structural phase transition with a second-order magnetic transition. This coincidence is achieved by careful compositional tuning and is a technique which provides a criterion for enhancing the GMCE in this system. Thus, for Ni 55.2 Mn 18.6 Ga 26.2 , we report an entropy change S m = −20.4 J kg −1 K −1 at 317 K in a field of 5 T. This shape memory system also has the added advantage of being formed from inexpensive, nontoxic constituents. With a working temperature at and above room temperature, it appears to be a most promising candidate for practical room temperature magnetic refrigeration.

Detailed measurements of the field- and temperature-dependent ac susceptibility and magnetization of LaMnO3 substituted with 5 at.% of the divalent cation Mg are presented. This system is a semiconducting ferromagnet at low temperature; in particular, analysis of these data yields Tc = 147.2±0.2 K, with critical exponents δ = 4.75±0.15 (from the field dependence of the susceptibility along the `crossover' line, and confirmed by measurements along the critical isotherm), γ + β = 1.75±0.05 (from the temperature dependence of the crossover line) and γ = 1.39±0.05 (from the temperature dependence of the susceptibility along the same line). Within experimental uncertainty these exponent values agree with those predicted by the isotropic, three-dimensional Heisenberg model. Nevertheless this system exhibits some unusual characteristics, specifically in the temperature dependence of the (low-) field-cooled and zero-field-cooled magnetization. The latter have been modelled by a Preisach-based approach, which helps to resolve a ubiquitous dilemma in the doped manganites, viz. the appearance of a technical hardness irreconcilable with low coercive field values. A possible origin for the large, reversible component in the response below Tc is presented.

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