Manganese-nickel (Mn-Ni) oxide films were electrodeposited on a graphite sheet in a bath consisting of manganese acetate and nickel chloride, and the structural, morphological, and electrochemical properties of these films were investigated. The electrodeposited Mn-Ni oxide films had porous structures covered with nanofibers. The X-ray diffractometer pattern revealed the presence of separate manganese oxide (γ-MnO2) and nickel oxide (NiO) in the films. The electrodeposited Mn-Ni oxide electrode exhibited a specific capacitance of 424 F/g in Na2SO4 electrolyte. This electrode maintained 86% of its initial specific capacitance over 2000 cycles of the charge-discharge operation, showing good cycling stability.
Nickel-cobalt (Ni-Co) oxide thin films were electrodeposited onto copper substrates in an electrolyte containing cobalt chloride and nickel chloride, and the electrochemical capacitor behaviors of these films were investigated. The XRD pattern revealed that the electrodeposited Ni-Co oxide thin film was comprised of NiCo 2 O 4 . In the SEM image, the electrodeposited Ni-Co oxide film was covered with hexagonal and cubical shaped particles. The electrodeposited Ni-Co oxide electrode exhibited a specific capacitance of 148 F/g at a scan rate of 20 mV, and the current density was fairly stable over 200 cycles. The charge-discharge test confirmed that capacitance of the electrodeposited Ni-Co oxide electrode resulted from the electric double layer capacitance and pseudocapacitance.
The nonlinear absorption in nanostructured Ni-Ti alloys, fabricated by electrochemical deposition, was investigated at 532 and 1064 nm. The type of nonlinear absorption (saturable or reverse saturable absorption) was observed to depend on the laser intensity as well as on the nanoparticle size. The nanostructured Ni-Ti alloys comprising particle mean diameters of 20 and 30 nm exhibited large three-photon absorption (3PA coefficient approximately 10(6) cm(3)/GW(2)) and large two-photon absorption (2PA coefficient approximately 10(5) cm/GW) at 532 nm, respectively. The observed change over from reverse saturable absorption to saturable absorption at high peak intensities has qualitatively been analyzed by the excited-state theory of conduction electrons.
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