In this report, PEDOT composite films were prepared by in situ electrochemical polymerization. 1-Ethyl-3-methylimidazole bis(trifluoromethylsulfonyl)imide (EMI-TFSI) was used as an ionic liquid dopant for PEDOT:PSS films. Subsequently, these PEDOT:PSS/EMI-TFSI films were compared with PEDOT:PSS films based on their morphology, structure, electrochromic properties, and optical properties at different deposition voltages and deposition times. It was observed that the addition of EMI-TFSI enhanced all the aforementioned properties of the films. PEDOT:PSS/EMI-TFSI films were seen to have a larger ion diffusion coefficient (1.38 × 10−20 cm2·s−1), a wider color change range (43.48%), a shorter response time (coloring response time = 1.2 s; fade response time = 2 s), and a higher coloring efficiency (189.86 cm2·C−1) when compared with normal PEDOT:PSS films. The introduction of EMI-TFSI in the films ultimately resulted in superior electrochemical and optical properties along with higher stability.
Poly(3,4‐ethylene dioxythiophene) (PEDOT) is a promising electrochromic material in many practical application, such as smart windows and displays. However, there are still difficulties in currently realizing green manufacturing, high coloration efficiency, and rapid response. Herein, in‐situ electrochemical polymerization of PEDOT:PSS/Reline films was suggested in aqueous solution. Deep eutectic solvents (DES) composed of choline chloride and urea (Reline) were employed as green solvents in reaction system and used as dopants for the PEDOT:PSS. The as‐prepared PEDOT:PSS/Reline films exhibited remarkable electrochromic properties, including great ion diffusion coefficient, fast reaction time (coloration response time was 1.4 s), prominent transmittance modulation (38%), high coloration efficiency (223 cm2/C) and excellent cyclic stability. Impressively, doping of Reline cannot only provide a green polymerization environment, but also significantly boost the electrochromic properties.
Owing to their biocompatibility, chemical stability, film-forming ability, cost-effectiveness, and excellent electroactive properties, poly(vinylidene fluoride) (PVDF) and PVDF-based polymers are widely used in sensors, actuators, energy harvesters, etc. In this review, the recent research progress on the PVDF phase structures and identification of different phases is outlined. Several approaches for obtaining the electroactive phase of PVDF and preparing PVDF-based nanocomposites are described. Furthermore, the potential applications of these materials in wearable sensors and human energy harvesters are discussed. Finally, some challenges and perspectives for improving the properties and boosting the applications of these materials are presented.
Extreme disasters may cause damage to energy system's components and transportation networks. How to achieve a rapid restoration of power supply is crucial. A coordinated post-disaster recovery and assessment method for the integrated electricity-gas-transportation system is proposed in this paper, and a repair sequence assessment model for the damaged road in transportation network based on topology and operational metrics is also established. Then, considering the dynamic changeability of the transportation network status, a rolling-updated model for dynamic road restoration and repair crew scheduling is proposed. Finally, we propose the coordinated post-disaster recovery and assessment model of electricity-gas-transportation system, in which the modified alternating direction multiplier of method is applied to solve. The impact of the transportation network repair process on system load recovery under different perspectives is verified by arithmetic examples.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.