Ag2O/g-C3N4 composites synthesized
in this study were applied in the photocatalytic degradation of phenol
under UV- and visible-light irradiation. X-ray diffraction, Fourier
transform infrared spectroscopy, X-ray photoelectron spectroscopy,
and transmission electron microscopy analysis demonstrated that Ag2O nanoparticles were well distributed on the surface of g-C3N4, and the heterostructure of Ag2O/g-C3N4 was formed. Compared with pure g-C3N4 and Ag2O, the Ag2O/g-C3N4 composite (8:1) displayed much higher photocatalytic
activities in phenol degradation under UV- and visible-light irradiation.
The degradation rate constant of 8:1 was 0.069 min–1 under visible light, which was almost 230 and 2.1 times more than
that of pure g-C3N4 and Ag2O, respectively.
Moreover, the formation of a certain amount of Ag0 on the
surface of Ag2O under illumination contributed to the high
stability of Ag2O/g-C3N4 photocatalysts.
It was also found that photogenerated holes during the photocatalytic
process played the predominant role in phenol degradation. The improved
photochemical reactivities were attributed to the formation of the
heterostructure between Ag2O and g-C3N4, the strong visible-light absorption, and the high separation efficiency
of photoinduced electron–hole pairs resulting from the highly
dispersed Ag2O particles.
To simply and effectively enhance the conversion capability of wearable thermoelectric textiles, a two-step in situ method is adopted to fabricate dual-shell photothermoelectric textiles which is made of polypropylene fibers with a photo-thermal layer (PPy) and a thermoelectric layer (PEDOT:Tos). The PPy is tailored to achieve high temperature and photothermoelectric effects. The PPy layer can significantly increase the photothermal conversion efficiencies of as-prepared fabric. The optimized photothermoelectric fabric can improve the generated voltage output from 294.13 to 536.47 μV under the infrared light, and its power density is up to 13.76 nW•m −2 . A flexible photothermoelectric strip composed of as-prepared fabric coated with Ag particles and textile substrates with low thermal conductivity shows a voltage output of 2.25, 0.677, and 0.183 mV and a power output of 0.7031, 0.0636, and 0.0049 nW under IR light, sunlight, and on the arm, respectively. The photothermoelectric fabrics display potential as to a new smart wearable device for converting light and electricity.
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