Although there has been significant progress in the development of transition-metal-catalyzed hydrosilylations of alkenes over the past several decades, metal-free hydrosilylation is still rare and highly desirable. Herein, we report a convenient visible-light-driven metal-free hydrosilylation of both electron-deficient and electron-rich alkenes that proceeds through selective hydrogen atom transfer for Si-H activation. The synergistic combination of the organophotoredox catalyst 4CzIPN with quinuclidin-3-yl acetate enabled the hydrosilylation of electron-deficient alkenes by selective Si-H activation while the hydrosilylation of electron-rich alkenes was achieved by merging photoredox and polarity-reversal catalysis.

A visible-light-induced highly selective alkylation and amination of unactivated C(sp 3 )-H bonds via the synergistic effects of an organo-photoredox catalyst and a bromine-based hydrogen atom transfer agent has been developed by applying CH 2 Br 2 as both the solvent and the bromine radical source. Our study offers a new paradigm for the direct synthesis of valuable compounds from abundant alkane feedstocks in a convenient and metal-free manner.

The Sanyangzhuang site, Henan Province, China, has a 12‐m‐deep stratigraphic sequence with remains from the Tang (A.D. 618–907), late Western Han (ca. 140 B.C.–A.D. 23), Warring States (475–221 B.C.), Late Neolithic or Early Bronze Age (ca. 5000–1500 B.C.), Middle Holocene, and Early Holocene times. All of the paleosols are deeply buried. We investigate four issues relevant to the archaeology of the lower Yellow River Valley. First, we confirm that the Yellow River flowed north toward Bohai Bay throughout most of the Holocene. Second, we expand understanding of Holocene paleoenvironments. Long episodes of landscape stability punctuated by brief periods of Yellow River flooding represent the dominant environmental pattern. Third, we investigate how the complex relationships between climate, culture, and the environment affect Yellow River flooding, which in turn shapes Chinese civilization and history. Flooding in late Western Han times affected a vast area of north‐central China; this catastrophe contributed to the downfall of the late Western Han Dynasty. Finally, this research sheds light on the role of Yellow River alluviation in site burial and preservation. Rapid alluviation in the region has buried many archaeological sites. Settlement pattern research needs to take seriously the limitations placed on site visibility in quickly aggrading floodplains. However, gentle alluviation has also preserved settlements and entire landscapes providing unparalleled opportunities to explore the archaeological and historical record of the lower Yellow River Valley.

An unprecendented direct alkylation of unfunctionalized allylic/benzylic sp3 C–H bonds via photoredox induced radical cation deprotonation is disclosed.