In comparison of GR and CLF, DC showed no statistical difference in both curing modes. However, dual and self-cured GR has statistically higher Tg values and lower percentage of softening in ethanol than CLF. Polymerization characteristics of dual-cure core build-up composites have superiority in dual-cured mode than self-cured.
A ceramic sample of a layered cuprate of
Tl2Ba2Ca2Cu3Ox and
Tl2Ba2Ca1Cu2Ox, so-called
Tl-based 2223 and 2212 compounds, was investigated by the measurement of the dielectric constants
(ε′ and
ε′′), the dielectric
loss (tanδ), and the
conductivity (σac)
as a function of temperature (80–300 K) and frequency (100 Hz–10 MHz). A negative
capacitance phenomenon has been observed and it is believed that the negative
capacitance effect is due to the polarization effect. The negative dielectric constant
has been calculated from the negative capacitance. The dielectric constant
(ε′) and the
dielectric loss (tanδ)
show strong dispersions at lower frequencies. The dielectric properties of the sample were
found to have strong frequency and temperature dependence.
Nickel tungsten alloy tapes (Ni—5 at% W, 10 mm wide, 80 µm thick, biaxially textured) used in second-generation high temperature superconductor (2G-HTS) technology were laser-processed in air with ultraviolet ps-laser pulses (355 nm wavelength, 300 ps pulse duration, 250–800 kHz pulse repetition frequency). By employing optimized surface scan-processing strategies, various laser-generated periodic surface structures were generated on the tapes. Particularly, distinct surface microstructures and nanostructures were formed. These included sub-wavelength-sized highly-regular hexagonally-arranged nano-protrusions, wavelength-sized line-grating-like laser-induced periodic surface structures (LIPSS, ripples), and larger irregular pyramidal microstructures. The induced surface morphology was characterized in depth by electron-based techniques, including scanning electron microscopy (SEM), electron back scatter diffraction (EBSD), cross-sectional transmission electron microscopy (STEM/TEM) and energy dispersive X-ray spectrometry (EDS). The in-depth EBSD crystallographic analyses indicated a significant impact of the material initial grain orientation on the type of surface nanostructure and microstructure formed upon laser irradiation. Special emphasis was laid on high-resolution material analysis of the hexagonally-arranged nano-protrusions. Their formation mechanism is discussed on the basis of the interplay between electromagnetic scattering effects followed by hydrodynamic matter re-organization after the laser exposure. The temperature stability of the hexagonally-arranged nano-protrusion was explored in post-irradiation thermal annealing experiments, in order to qualify their suitability in 2G-HTS fabrication technology with initial steps deposition temperatures in the range of 773–873 K.
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