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Fishing with the aid of plant toxins was formerly very common in tropical Africa. Today this easy method of fishing is still practised in remote areas. The method is simple: the poisonous ingredients are pounded and thrown into a pool or dammed‐up sections of a small river. After a short time the fish begin to rise to the surface and can then readily be taken by hand. The fish can be eaten without health problems. The main active compounds are saponins, rotenoids and diterpene esters. Such biologically active plants are of great interest to scientists of various disciplines. Some of these plants provide important insecticides, many play an important part in traditional medicine and in preparation or arrow poisons. 258 fish‐poisoning plants are presented, based on 25 years of field research by the author in tropical Africa and evaluations of herbarium notes. 10–20 per cent of the fishing poisons are probably still unknown. They are spread among 167 plant genera and 60 families. The evaluation shows a clear dominance of the Leguminosae (Caesalpiniaceae, Mimosaceae, Papilionaceae) in the hierarchy of the fish poisoning plants. It is also remarkable that a great proportion are in the Euphorbiaceae.

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