In this work, a series of Cu(ii)-doped Bi2WO6 nanomaterials with good photo-response properties were facile synthesized and used to obtain efficient peroxymonosulfate (PMS) activation activity for norfloxacin (NOF) removal under visible LED light irradiation.

In this study, the removal performance for BPA by PMS activated by the LCFO catalyst in a heterogeneous catalytic system was investigated.

A series of copper doping LaFeO3 perovskite (LaCuxFe1−xO3, LCFO, x = 0.1, 0.4, 0.5, 0.6, 0.9) are successfully synthesized by the sol-gel method under mild conditions. In this study, it is applied for the activation of peroxymonosulfate (PMS) for bisphenol A (BPA) removal. More than 92.6% of BPA was degraded within 30 min at 0.7 g/L of LCFO and 10.0 mM of PMS over a wide pH range with limited leaching of copper and iron ions. The physical–chemical properties of the catalysts were demonstrated by using X-ray diffraction (XRD), N2 adsorption–desorption isotherms, scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Furthermore, the effects of catalyst dosage, PMS concentration, initial pH value, and inorganic anions on the LCFO/PMS system were fully investigated. Quenching experiments were performed to verify the formation of reactive oxidant species, which showed that the radical reaction and mechanisms play a great role in the catalytic degradation of BPA. The perovskite LCFO is considered a stable, easy to synthesize, and efficient catalyst for the activation of PMS for wastewater treatment.