No abstract

The aim of this experiment is to estimate the relative ratio of geometric isomers of Dibenzalacetone that was prepared via the crossed-aldol condensation by reacting benzaldehyde with acetone. Dibenzalacetone was synthesized in the lab from benzaldehyde and acetone under basic conditions. The GC-MS was used to relate the molar mass of the product. Thin layer chromatography was used to visualize the relative RF factor for each isomer. Uv-Vis instrument showed three peaks that were assigned to each isomer. And the FT-IR was used for the assignment of the vibrational modes of each isomer. The relative ratio of trans-trans, Cis-trans, and Cis-Cis was 59.87%, 26.53%, and 13.60% respectively with the aid of FT-IR instruments peak assignments were made for the vibrational frequency of the functional groups. For organic laboratory setups and practices, the fragments from the MS spectrum of DBA can be explained based on cleaving or rearrangement in gas phase by mechanisms known as α-cleavage, β-cleavage, and Rearrangement migration.

The periodic table of chemistry contains all synthetic and naturally occurring elements. The elements are arranged in seven horizontal periods from left to right with increasing atomic number. The periodic table is divided into two groups: metals and nonmetals, within elements moving from left to right, the elements get less metallic, culminating in nonmetals on the far right side of the table. Further, the elements are also arranged in eight vertical columns or groups for those with similar physical and chemical properties. A model equation has been developed based on the 8-group and the 7-periods from which trends of elements has been calculated. Among the trends in the periodic table that were calculated are ionization energy, atomic size and effective nuclear charge. It has been discovered that the calculated theoretical values from the model equation rhyme well with the actual values for each element with few exceptions.

This study aims to explore the potential use of treated wastewater in irrigating fodder crops and its effects on protein contents. A comparison of the protein contents in intercropped fodder plants irrigated with fresh water, and rainfall water, against those irrigated with treated grey water was performed under Palestinian climate conditions. Field experiments with different intercropping mixing ratios were carried out in 2017–2019 at the National Agricultural Research Centre in Palestine (NARC). Measurements of the nutritional value of each mixture specifically the protein contents were carried out to get the optimal and best conditions for preparing animal feed crops with three different water sources used. For alfalfa with vetch, the best result for protein percentages was (on average) obtained from the rain-fed experiment (17.1% protein) followed by the freshwater experiment (12.9% protein) and then by the treated grey-water experiment (12.6% protein). It appears that the best result for alfalfa with barley for protein percentages was (on average) obtained from the treated grey-water experiment (13.0% protein) followed by the freshwater experiment (11.1% protein) and then by the rain-fed experiment (10.5% protein). Statistical analysis of the data showed that percent protein for each specific mixing ratio resulted in significant differences in the protein % for the those irrigated with fresh water compared with the other types of water. The highest protein % was found to be for that irrigated with fresh water (31.9 for 10/90 alfalfa/barley ratio) followed by that irrigated with treated grey water (28.4 for 20/80 alfalfa/barley ratio) and then for the 30/70 ratio irrigated with treated wastewater (22.5%), and then for the 100/0 ratio of alfalfa/barley irrigated with rainwater (19.0). Overall, results of this study showed that cereal-legume intercropping irrigated with treated grey water can be used as a suitable management strategy for producing high-quality and high-quantity forage. Furthermore, the use of treated water can reduce the already strained demand on fresh water due to increase in population among other factors.