Across the globe, the quest for clean water is escalating for both households as well as agricultural exigencies. With the industrial revolution and swift population growth, the contamination of natural water bodies has impacted the lives of more than two billion people around the world. A spectrum of water-saving solutions has been examined. Nonetheless, most of them are either energy-inefficient or limited to only a particular region. Thus, the pursuit of clean and potable drinking water is an assignment that invites collective discourse from scientists, policymakers, and innovators. In this connection, the presence of moisture in the atmosphere is considered one of the major sources of potential freshwater. Thus, fishing in atmospheric water is a mammoth opportunity. Atmospheric water harvesting (AWH) by some plants and animals in nature (particularly in deserts or arid regions) at low humidity serves as an inspiration for crafting state-of-the-art water harvesting structures and surfaces to buffer the menace of acute water scarcity. Though a lot of research articles and reviews have been reported on bioinspired structures with applications in water and energy harvesting, the area is still open for significant improvisation. This work will address the multidimensional-based AWH ability of natural surfaces or fabricated structures without the involvement of toxic chemicals. Moreover, the review will discuss the availability of clean technologies for emulating fascinating natural surfaces on an industrial scale. In the end, the current challenges and the future scope of bioinspired water harvesters will be discussed for pushing greener technologies to confront climate change.