The supercontinent of Pangaea formed through the diachronic collision of Laurussia and Gondwana during the Late Paleozoic. Whilst magmatism associated with its formation is well documented in the Variscan orogeny of Europe and Alleghanian orogeny of the USA, little is known about the Sonora orogeny of Northern Mexico. This paper reports geochronology (U-Pb zircon), whole rock geochemistry and Lu-Hf zircon isotope data on basement cores from the Western Gulf of Mexico, that are used to develop a tectonomagmatic model for pre-to post-Pangaea amalgamation. Our results suggest the existence of three distinct phases of magmatism, produced during different stages of continental assembly and disassembly. The first phase consists of Early Permian (294-274 Ma; n= 3) granitoids with geochemical signatures indicative of a continental arc tectonic setting. This phase formed on the margins of Gondwana during the closure of the Rheic Ocean, prior to the final amalgamation of Pangaea. It likely represents a lateral analogue of Late Carboniferous-Early Permian granitoids that intrude the Acatlán and Oaxacan Complexes. The second phase of magmatism includes Late Permian-Early Triassic (263-243 Ma; n= 13) granitoids with suprasubduction geochemical affinities. However, Lu-Hf isotope data indicate that these granitoids formed from crustal anatexis, with ɛHf values and two-step TDM(Hf) model ages comparable to the Oaxaquia continental crust that they intrude. This phase of magmatism is likely to be related to coeval granitoids in the Oaxaca area and Chiapas Massif. We interpret it to reflect late-to post-collisional magmatism along the margin of Gondwana following the assembly of Pangaea. Finally, the third phase of magmatism includes Early-Middle Jurassic (189-164 Ma; n= 2) mafic porphyries that could be related to the synchronous supra-subduction magmatism associated with the Nazas arc. Overall, our results are consistent with Pangaea assembly through diachronous collision of Laurussia and Gondwana during subduction of the Rheic Ocean. They suggest that post-orogenic magmatism in the western termination of the Rheic suture occurred under the influence of a Panthalassan subduction zone, before opening of the Gulf of Mexico.

Sandstone petrography, detrital zircon geochronology, and sedimentology of Lower Cretaceous to Paleocene strata in the Cuicateco terrane of southern Mexico indicate an evolution from extensional basin formation to foreland basin development. The Early Cretaceous extensional basin is characterized by deposition of deep-marine fans and channels, which were mainly sourced from Mesoproterozoic and Permian crystalline rocks of the western shoulder of the rift basin. Some submarine fans, especially in the northern Cuicateco terrane, record an additional source in the Early Cretaceous (ca. 130 Ma) continental arc. The fans were fed by fluvial systems in updip parts of the extensional basin system. The transition from middle Cretaceous tectonic quiescence to Late Cretaceous shortening is recorded by the Turonian–Coniacian Tecamalucan Formation. The Tecamalucan Formation is interpreted as pre-orogenic deposits that represent submarine-fan deposits sourced from Aptian–Albian carbonate platform and pre-Mesozoic basement. The foreland basin in the Cuicateco terrane was established by the Maastrichtian, when foredeep strata of the Méndez Formation were deposited in the Cuicateco terrane, Veracruz basin, and across the western Gulf of Mexico, from Tampico to Tabasco. In the Zongolica region, these strata were derived from a contemporaneous volcanic arc (100–65 Ma) located to the west of the basin, the accreted Guerrero terrane (145–120 Ma), and the fold belt itself. By the Paleocene, sediments were transported to the foreland basin by drainages sourced in southwestern Mexico, such as the Late Cretaceous magmatic rocks of the Sierra Madre del Sur, and the Chortis block.

Moderately thermophilic (Tmax, ~55 °C) methanogens are identified after extended enrichments from temperate, tropical and low-temperature environments. However, thermophilic methanogens with higher growth temperatures (Topt ≥ 60 °C) are only reported from high-temperature environments. A microcosm-based approach was used to measure the rate of methane production and methanogen community structure over a range of temperatures and salinities in sediment from a temperate estuary. We report short-term incubations (<48 h) revealing methanogens with optimal activity reaching 70 °C in a temperate estuary sediment (in situ temperature 4–5 °C). While 30 °C enrichments amended with acetate, H2 or methanol selected for corresponding mesophilic trophic groups, at 60 °C, only hydrogenotrophs (genus Methanothermobacter) were observed. Since these methanogens are not known to be active under in situ temperatures, we conclude constant dispersal from high temperature habitats. The likely provenance of the thermophilic methanogens was studied by enrichments covering a range of temperatures and salinities. These enrichments indicated that the estuarine sediment hosted methanogens encompassing the global activity envelope of most cultured species. We suggest that estuaries are fascinating sink and source environments for microbial function study.

We redefine the “Chontal arc” of the southern Isthmus of Tehuantepec, Mexico, as the Chontal allochthon. The Chontal assemblage is composed of Upper Cretaceous low-grade metavolcanic and metasedimentary rocks included in the Chivela lithodeme. By means of field observations, laser-ablation detrital zircon geochronology, and trace-element geochemistry, we constrained the provenance and tectonic setting of these rocks. We concluded that they form an allochthon emplaced during a Paleogene transpressive event. Basement structure in the greater Oaxaca-Chiapas area was assessed by qualitative interpretation of Mexican State aeromagnetic maps. Chivela lithodeme sediments include a contribution from Albian–Turonian volcanic arc rocks no longer present in the region, likely sourced from the Chortís block or from the Greater Antilles Arc as it collided with southern Yucatan. Maastrichtian basic intrusive units, basalt flows, and pillow lavas with pelagic sediments in the Chontal are subalkaline, plotting in the normal mid-ocean-ridge basalt (N-MORB) field of discrimination diagrams. The igneous rocks are interpreted as pertaining either to the inception of the paleo–Motagua fault zone (left step in the fault trace), or to local backarc extension behind the Chortís block just before it began to migrate eastward, in a basin we call the Chontal basin. The Chontal allochthon was thrust northward onto parautochthonous strata flanking the Mixtequita and Chiapas Massif basements. Chontal allochthon rocks were later intruded by Miocene granitoids related to the inception of Cocos plate subduction arc magmatism. Rocks of the Chontal allochthon have been previously linked to the Cuicateco belt of eastern Oaxaca, but this is challenged here on the basis of lithologic type, chronology, tectonic associations, structural styles, and discontinuous anomaly trends in aeromagnetic maps.

<div>Geochronology appendix</div>