In a recent commentary, J. M. Kosterlitz described how D. Thouless and he got motivated to investigate melting and suprafluidity in two dimensions [Kosterlitz JM (2016) J Phys Condens Matter 28:481001]. It was due to the lack of broken translational symmetry in two dimensions-doubting the existence of 2D crystalsand the first computer simulations foretelling 2D crystals (at least in tiny systems). The lack of broken symmetries proposed by D. Mermin and H. Wagner is caused by long wavelength density fluctuations. Those fluctuations do not only have structural impact, but additionally a dynamical one: They cause the Lindemann criterion to fail in 2D in the sense that the mean squared displacement of atoms is not limited. Comparing experimental data from 3D and 2D amorphous solids with 2D crystals, we disentangle Mermin-Wagner fluctuations from glassy structural relaxations. Furthermore, we demonstrate with computer simulations the logarithmic increase of displacements with system size: Periodicity is not a requirement for Mermin-Wagner fluctuations, which conserve the homogeneity of space on long scales.Mermin-Wagner fluctuations | 2D ensembles | glass transition | phase transition | confined geometry F or structural phase transitions, it is well known that the microscopic mechanisms breaking symmetry are not the same in two and in three dimensions. Whereas 3D systems typically show first-order transitions with phase equilibrium and latent heat, 2D crystals melt via two steps with an intermediate hexatic phase. Unlike in 3D, translational and orientational symmetry are not broken at the same temperature in 2D. The scenario is described within the Kosterlitz, Thouless, Halperin, Nelson, Young (KTHNY) theory (1-5), which was confirmed (e.g., in colloidal monolayers) (6, 7). However, for the glass transition, it is usually assumed that dimensionality does not play a role for the characteristics of the transition, and 2D and 3D systems are frequently used synonymously (8-12), whereas differences between the 2D and 3D glass transition are reported in ref. 13.In the present work, we compare data from colloidal crystals and glasses and show that Mermin-Wagner fluctuations, well known from 2D crystals, are also present in amorphous solids (14, 15). Mermin-Wagner fluctuations are usually discussed in the framework of long-range order (magnetic or structural). However, in the context of 2D crystals, they have also had an impact on dynamic quantities like mean squared displacements (MSDs). Long before 2D melting scenarios were discussed, there was an intense debate as to whether crystals and perfect longrange order (including magnetic order) can exist in 1D or 2D at all (16)(17)(18)(19). A beautiful heuristic argument was given by Peierls (17): Consider a 1D chain of particles with nearest neighbor interaction. The relative distance fluctuation between particle n and particle n + 1 at finite temperature may be ξ. Similar is the fluctuation between particle n + 1 and n + 2. The relative fluctuation between second nearest neig...
This paper reports an experimental study of the preparation of screened printed dielectric materials having high dielectric constants and a controlled temperature characteristic. The techniqueuses mixturesof sintered bodies which havedifferent Curie points and which retain their identity after processing. Barium-strontium and barium-lead titanate mixtures have been prepared having a dielectric constant of about 500. This process has been used to produce negative-positive-zero, negative, and positivethermal coefficient bodies over various temperature ranges.
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