A low-temperature process to synthesize and print photoactive
TiO2 nanofilms onto polymeric substrates using a modified
desktop
inkjet printer is presented. The coated substrates were assembled
in a microfluidic device for photocatalytic studies fabricated by
selective transmission laser welding. The synthesized TiO2 showed a competitive activity compared with commercial TiO2 nanopowders. Furthermore, the coated catalyst remained active and
intact even after a long-term reaction run. The inkjet printing method
can be utilized for the efficient immobilization of catalytic films
onto reactor walls in the design of continuous flow reactors. A dispersed
TiO2 sol was prepared by the thermohydrolysis of TiCl4 below 100 °C.
The resulting sol was stabilized by using ethylene glycol and directly
printed onto the substrate without further heat processing. The printability
and colloidal stability of the inks were assessed by measuring their
rheological and interfacial properties. X-ray powder diffraction (XRD)
analysis identified the synthesized TiO2 as pure anatase
nanosized particles (∼4.5 nm) verified by transmission electron
microscopy (TEM). The photocatalytic activity of the printed layers
was studied in the microreactor based on the degradation of methylene
blue. Inkjet printing proved to be a customizable technique for coating
active nanocatalysts. The overall process presented here is cost-effective
and efficient in manufacturing flexible lightweight microreactors
coated with highly tunable TiO2 catalytic films.
A series of heterogeneous catalysts including different molar ratios of CaO/talc was synthesized to study the transesterification reaction of canola oil and methanol under different reaction conditions. Characterization and kinetic results revealed that the activity of this catalyst was enhanced due to the increase of CaO/talc molar ratio value leading to an improvement in the biodiesel production. Moreover, the effect of various parameters on the activity of the undertaken catalysts was studied in order to determine the optimum process conditions. Leaching measurements and the durability of the CaO/talc catalyst under several reaction cycles were evaluated and proved it to be a stable catalyst.
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