We examine a series of closely related, relatively inert, cyclic
aliphatic solutescyclohexane, methylcyclohexane, 1,1-dimethylcyclohexane,
1,4-trans-dimethylcyclohexane,
1,4-cis-dimethylcyclohexane, trans-decalin,
and
cis-decalinin a nematic solvent and demonstrate that
their orientational ordering can be accurately described
in
terms of purely hard-body interactions with the solvent molecules.
These interactions are treated explicitly in the
context of a statistical mechanical approximation wherein the
orientational correlations among the solvent molecules
are not taken into account directly. We test the theory by
predicting the observed order parameters of the aliphatic
solutes as determined with deuterium nuclear magnetic resonance.
The utility and limitations of a description of
solute ordering derived exclusively from hard-body interactions is
discussed.
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