Photonic crystal resonators with the C4v symmetry were designed and fabricated on quantum cascade lasers with a strain-compensated multiple quantum well to achieve single-mode and vertical surface emission at 4.32 μm. Their fabrication accuracy was confirmed by high-resolution reflection spectroscopy. The maximum output power was 10 mW at 77 K. A far-field pattern with a small divergence angle below 1 degree was observed. Its main peak had a donut shape, which was attributed to the spatial symmetry of the resonance mode of the photonic crystal.

We quantified the thermal resistance of quantum cascade lasers (QCLs) using their structure functions and increased the laser output by employing ridge structures in which thermal resistance was reduced. To improve heat properties, three different QCL devices were prepared as follows. One was a device whose ridge was covered with SiO 2 , another was a device whose ridge was embedded with Au, and the other was a device whose ridge was embedded with Cu. The temperature distributions were measured with a thermoviewer and were analyzed with threedimensional simulations. From the results, improved heat dissipation by embedding the ridge was clarified. Furthermore, the structure functions obtained by static mode measurement suggested that the thermal resistance was improved from 9.3 to 6.5 K W −1 by embedding the ridge. As a result of the improvement, the QCL with the Au-embedded ridge had a 1.5-fold higher laser power than the QCL with the SiO 2 -covered ridge.

In order to develop NiMnGa/polymer composite materials, a production of single-crystal-like NiMnGa particles is important and should be developed for better quality. Although mechanical pulverization is a promising method by utilizing intrinsic intergranular brittleness of NiMnGa polycrystalline ingots, the amount of lattice defects introduced during mechanical crushing needs to be minimized. This must be achieved by enhancement of intergranular brittleness of NiMnGa particles. In this study, the effect of Bi addition on the compressive fracture behavior of polycrystalline Ni50Mn28Ga22 was investigated where Bi was expected to be segregated to the grain boundaries in NiMnGa, similar to Bi segregation to the grain boundaries in Ni. It was found that only intergranular fracture was observed in Ni50Mn28Ga22 polycrystals with 0.3 at.% Bi addition, although a mixture of intergranular and transgranular fracture was observed in Bi-free Ni50Mn28Ga22 polycrystal. Microalloying of Bi into NiMnGa enhances intergranular embrittlement. A number of spherical particles of Bi were confirmed on the fractured surface of Bi-doped NiMnGa polycrystals. The formation of Bi particles is a proof of the grain boundary segregation of Bi in NiMnGa.

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We fabricated surface-emitting quantum cascade lasers with photonic crystal resonators whose active layers were strain-compensated InGaAs/AlInAs multiple quantum wells to operate at 4.3 μm. We tested two kinds of square-lattice photonic crystals consisting of circular and pentagonal InGaAs cylinders as a unit structure. We examined their output power and far-field pattern to find that both of them were improved by lowering the photonic-crystal symmetry to achieve a high extraction efficiency. The maximum output power was 50 mW at 77 K and the far-field pattern was a single peak with a divergence angle smaller than 1° for the pentagonal cylinder structure. In addition, we attributed the lasing mode to a B2-symmetric (quadrupole) eigen state on the Γ point for the circular cylinder structure by observing the polarization dependence of the far-field pattern and comparing it with calculations by the k·p perturbation method.