In this paper, two methods, organic solvent dispersive liquid-liquid microextraction (OS-DLLME) and ionic liquid dispersive liquid-liquid microextraction (IL-DLLME), coupled with high-performance liquid chromatography have been critically compared and introduced for the analysis of the eight coumarin compounds (psoralen, isopsoralen, bergapten, isobergapten, oxypeucedanin, imperatorin, osthole, and isoimperatorin) in Radix Angelicae Dahuricae samples. Experimental conditions have been investigated for both OS-DLLME and IL-DLLME. Under optimal conditions, the detection limits of the eight coumarin compounds obtained by OS-DLLME and IL-DLLME ranged between 0.002-0.026 ng mL -1 and 0.013-0.66 ng mL -1 , respectively. The relative standard deviations (RSDs, n = 9) were lower than 8.7 and 8.4% with enrichment factors in the range of 145-380 and 130-230 folds for OS-DLLME and IL-DLLME, respectively. The results showed that there were no significant deviations between the two DLLME methods for the determination of the eight coumarin compounds. Both methods were simple, fast, efficient, and inexpensive. However, compared with IL-DLLME, the OS-DLLME technique exhibited a higher extraction capacity for the eight target analytes.
Based on the geological and the experimental data of the13#coal seam of Sun-Cun Coal Mine, the relationship curve between the geothermal heat in Sun-Cun coal mine and experimental wind speed has been fit out.According this and the laboratory experiments,the relational expression between the quantity of CO2 produced in the period of spontaneous combustion and the wind speed in the coal mine has been developed. The research results show that when the wind speed exceeds 2m/s,the quantity of CO2 produced has a sharp rising tendency.
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