A simple approach to wafer-scale self-cleaning antireflective hierarchical silicon structures is demonstrated. By employing the KOH etching and silver catalytic etching, pyramidal hierarchical structures were generated on the crystalline silicon wafer, which exhibit strong antireflection and superhydrophobic properties after fluorination. Furthermore, a flexible superhydrophobic substrate was fabricated by transferring the hierarchical Si structure to the NOA 63 film with UV-assisted imprint lithography. This method is of potential application in optical, optoelectronic, and wettability control devices.

We develop an efficient high-order boundary-element method with the mixed-Eulerian–Lagrangian approach for the simulation of fully nonlinear three-dimensional wave–wave and wave–body interactions. For illustration, we apply this method to the study of two three-dimensional steep wave problems. (The application to wave–body interactions is addressed in an accompanying paper: Liu, Xue & Yue 2001.) In the first problem, we investigate the dynamics of three-dimensional overturning breaking waves. We obtain detailed kinematics and full quantification of three-dimensional effects upon wave plunging. Systematic simulations show that, compared to two-dimensional waves, three-dimensional waves generally break at higher surface elevations and greater maximum longitudinal accelerations, but with smaller tip velocities and less arched front faces. For the second problem, we study the generation mechanism of steep crescent waves. We show that the development of such waves is a result of three-dimensional (class II) Stokes wave instability. Starting with two-dimensional Stokes waves with small three-dimensional perturbations, we obtain direct simulations of the evolution of both L2 and L3 crescent waves. Our results compare quantitatively well with experimental measurements for all the distinct features and geometric properties of such waves.

Solar distillation is emerging as a robust and energy-effective tool for water purification and freshwater production. However, many water sources contain harmful volatile organic compounds (VOCs), which can evaporate through the photothermal evaporators and be collected together with distilled water, or even be enriched in the distilled water. In view of the penetration of volatile organic compounds, herein, we rationally demonstrate a dual-scale porous, photothermal/ photocatalytic, flexible membrane for intercepting volatile organic compounds during solar distillation, which is based on a mesoporous oxygen-vacancy-rich TiO 2−x nanofibrous membrane (m-TiO 2−x NFM). The dual-scale porous structure was constructed by micrometer-sized interconnected tortuous pores formed by the accumulation of m-TiO 2−x nanofibers and nanometer-sized pores in the m-TiO 2−x individual nanofibers. Consequently, the membrane can sustainably in situ intercept VOCs by providing more photocatalytic reactive sites for collision (mainly by mesopores) and longer tortuous channels for prolonging VOC retention (mainly by micrometer-sized pores); thus, it results in less than 5% of phenol residual in distilled water. As a proof of concept, when the m-TiO 2−x NFM is employed to purify practical river water in an evaporation prototype under real solar irradiation, complex volatile natural organic contaminants can be effectively intercepted and the produced distilled water meets the drinking water standards of China. This development will promote the application prospects of solar distillation.

Here, a hierarchical porous NiO film/ITO glass bifunctional electrode has been prepared successfully via growing MOF-74 in situ on ITO, which shows outstanding cycle reversibility, excellent capacitance, and high coloration efficiency.