Soil chemical and topographic properties are two important factors influencing available micronutrient distribution of soil in the horizontal dimension. The objective of this study was to explore the relative influence of soil chemistry (including soil pH, soil organic matter, total nitrogen, available phosphorus, and available potassium) and topography (including elevation, slope, aspect, and wetness index) on the availability of micronutrients (Fe, Mn, Cu, Zn, and B) using structural equation modeling (SEM) at the watershed scale. To do this, levels of soil micronutrients, pH, soil organic matter, total nitrogen, available phosphorus, available potassium, and topographic factors were measured at 523 sampling points of Fanshi County on the Chinese Loess Plateau, and the spatial distribution of soil available micronutrients were analyzed by geostatistical method. The results showed that topography had both direct effects and indirect effect on some soil micronutrients, while the indirect effect indicated effects from topography on soil chemistry and then further on micronutrient concentration. Soil chemistry had direct effects on levels of all soil micronutrients, and topography had direct effects on levels of all micronutrients except for Cu and B, and indirect effects on Fe, Zn, and B. The direct effect of soil chemistry on Fe levels was greater than the total effects (including both direct and indirect) of topography. Topography had a stronger direct effect on Mn than soil chemistry, and topography had less direct but stronger total effects on Zn than soil chemistry. Soil chemistry directly influenced both Cu and B, but topography only influenced B in an indirect manner. The semivariance indicated that the micronutrients had moderate spatial dependency except for B which had weak spatial dependency. Within the spatial distribution of the micronutrients, there was a zone in the middle of the watershed with lower values than in the northern and southern areas for Fe, Mn, Zn, and B, which were related to the characteristics of topography and soil chemistry. These results may guide the management of soil micronutrients of the Chinese Loess Plateau and other similar regions in the world.

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The soil organic carbon (SOC) pool in farmland is changing rapidly due to human activities, thereby greatly affecting the regional and global environment, as well as influencing soil fertility and crop yields. The present study investigated the effects of underground coal mining on the regional SOC pool in farmland in the Jiuli Mining Area of Xuzhou City in China as a typical coal mining region based on field sampling, chemical analysis, model construction, and spatial analysis using the software of ArcGIS. The results showed that in the mining subsidence area, spatial variations in the SOC content and soil bulk density were mainly caused by structural factors (mining subsidence, subsidence waterlogging, and other structural factors due to coal mining) at a regional scale. SOC storage in farmland soil decreased sharply in non-waterlogged subsidence farmland and seasonally waterlogged subsidence farmland in the areas with mining, whereas the SOC storage increased in waterlogged wetland after coal mining. The SOC was reduced by 102,882 tonnes (32.81%) compared with the original SOC stock as a consequence of coal mining, and thus the effect of underground coal mining on the regional SOC pool in farmland was characterized as a carbon loss process. Land-use changes, soil degradation and erosion contributed almost equally to the carbon loss process in the study area. The results of this study may facilitate evaluations of low-carbon land reclamation and ecological compensation in mining areas.

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