Incorporating with inhomogeneous phases with high electroluminescence (EL) intensity to prepare smart meta-superconductors (SMSCs) is an effective method for increasing the superconducting transition temperature (Tc) and has been confirmed in both MgB2 and Bi(Pb)SrCaCuO systems. However, the increase of ΔTc (ΔTc = Tc ‒ Tcpure) has been quite small because of the low optimal concentrations of inhomogeneous phases. In this work, three kinds of MgB2 raw materials, namely, aMgB2, bMgB2, and cMgB2, were prepared with particle sizes decreasing in order. Inhomogeneous phases, Y2O3:Eu3+ and Y2O3:Eu3+/Ag, were also prepared and doped into MgB2 to study the influence of doping concentration on the ΔTc of MgB2 with different particle sizes. Results show that reducing the MgB2 particle size increases the optimal doping concentration of inhomogeneous phases, thereby increasing ΔTc. The optimal doping concentrations for aMgB2, bMgB2, and cMgB2 are 0.5%, 0.8%, and 1.2%, respectively. The corresponding ΔTc values are 0.4, 0.9, and 1.2 K, respectively. This work open a new approach to reinforcing increase of ΔTc in MgB2 SMSCs.
The smart meta-superconductor MgB2 and Bi(Pb)SrCaCuO increase the superconducting transition temperature (TC), but the changes in the transport critical current density (JC) and Meissner effect are still unknown. Here, we investigated the JC and Meissner effect of smart meta-superconductor MgB2 and Bi(Pb)SrCaCuO. The use of the standard four-probe method shows that Y2O3:Eu3+ and Y2O3:Eu3++Ag inhomogeneous phase significantly increase the JC, and JC decreases to a minimum value at a higher temperature. The Meissner effect was measured by direct current magnetization. The doping of Y2O3:Eu3+ and Y2O3:Eu3++Ag luminescent inhomogeneous phase causes a Meissner effect of MgB2 and Bi(Pb)SrCaCuO at a higher temperature, while the non-luminescent dopant reduces the temperature at which samples have Meissner effect. The introduction of luminescent inhomogeneous phase in conventional MgB2 and copper oxide high-temperature Bi(Pb)SrCaCuO superconductor increases the TC and JC, and Meissner effect is exerted at higher temperature. Therefore, smart meta-superconductivity is suitable for conventional and copper oxide high-temperature superconductors.
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