Secondary microplastics usually come
from the breakdown of larger
plastics due to weathering and environmental stress cracking of plastic
wastes. In the present study, 5013 plastic fragments were collected
from coastal beaches, estuary dikes, and lake banks in China. The
fragment sizes ranged from 0.2 to 17.1 cm, and the dominant polymers
were polypropylene and polyethylene. Cracks were observed on the surfaces
of 49–56% of the fragments. Based on the extracted crack images,
we proposed a general crack pattern system including four crack types
with specific definitions, abbreviations, and symbols. The two-dimensional
spectral analysis of the cracks suggests that the first three patterns
showed good regularity and supported the rationality of the pattern
system. Some crack metrics (e.g., line density) were closely correlated
with the carbonyl index and additives (e.g., phthalate esters) of
fragments. For crack investigation in field, we proposed a succinct
protocol, in which five crack ranks were established to directly characterize
the degree of cracking based on the line density values. The system
was successfully applied to distinguish the differences in crack features
at two representative sites, which indicates that crack pattern is
a useful tool to describe the morphological changes of plastic surfaces
in the environment.
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