In this work, iron oxide (Fe2O3) and titanium oxide (TiO2) doping (Fe2O3) thin films have been prepared by spray pyrolysis technique (SPT) on a glass substrate. We have studied the effects of various doping percentage of (TiO2) on (Fe2O3) optical and electrical properties. The optical parameters of the prepared films as absorbance, absorption coefficient, optical energy gap and refractive index have been calculated for all prepared films. D.C conductivity and Hall effect for all films are measured. The results showed that absorbance of prepared films decreases with increasing percentage of (TiO2) this lead to increase the energy gap and conductivity decreased with increasing of percentage of (TiO2) as well as the results showed throughout the study that all films have tow activation energy, its value increase with increasing of percentage of (TiO2). Hall effect measurement showed all films have n-type conductivity.