2-methylphenoxyacetic acid (2-MPA), 2-methyl-4-chlorophenxyacetic acid (MCPA) and 4-chlorophenoxyacetic acid (4-CPA) were imprinted to investigate the cross-selectivities of molecularly imprinted polymers (MIPs). The result indicates that 2-MPA, which is similar in shape, size and functionality with phenoxyacetic herbicides, are suitable to be used as a suitable template to prepare the MIPs for retaining phenoxyacetic herbicides. To study the ion-pair interactions between template molecules and functional monomer 4-vinylpiridine (4-VP), computational molecular modeling was employed. The data indicate that the cross-selectivities of MIPs for phenoxyacetic acid herbicides depend on the binding energies of complexes.

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Electrochemical regeneration of reduced nicotinamide adenine dinucleotide (NADH) is an extremely important challenge for the electroenzymatic synthesis of many valuable chemicals. Although some important progress has been made with modified electrodes concerning the reduction of NAD + , the scale-up is difficult due to mass transport limitations inherent to large-size electrodes. Here, we propose instead to employ a dispersion of electrocatalytically active modified microparticles in the bulk of a bipolar electrochemical cell. In this way, redox reactions occur simultaneously on all of these individual microelectrodes without the need of a direct electrical connection. The concept is validated by using [Rh(Cp*)(bpy)Cl] + functionalized surfaces, either of carbon felt as a reference material, or carbon microbeads acting as bipolar objects. In the latter case, enzymatically active 1,4-NADH is electroregenerated at the negatively polarized face of the particles. The efficiency of the system can be fine-tuned by controlling the electric field in the reaction compartment and the number of dispersed microelectrodes. This wireless bioelectrocatalytic approach opens up very interesting perspectives for electroenzymatic synthesis in the bulk phase.

Bipolar electrochemistry , symbolized by the two electrodes at the opposite sides of the picture, can trigger the bioelectrocatalytic reduction of the important enzymatic cofactor NAD+, as reported by Lin Zhang, Alexander Kuhn et al. in their Communication (e202111804). The reaction occurs on the negatively polarized side—indicated by the δ− sign—of surface‐modified catalytically active beads—illustrated by the planets—suspended in the bulk phase of an electrolyte. This wireless electrochemical approach allows a systematic tuning of the increase in conversion efficiency.

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