Three-dimensional (3D) microstructures are essential elements in various technological applications, including optical coatings, [ 1 , 2 ] tissue engineering scaffolds, [ 3 ] microfl uidics, [ 4 ] energy storage devices, [ 5 , 6 ] plasmonics, [ 7 ] and photonic crystals. [ 8 , 9 ] While conventional methods, such as photo lithography and electron beam lithography, are costly and ineffective in the generation of complex 3D patterns over large areas, unconventional methods based on soft lithography, such as nanoimprint lithography (NIL), [ 10 ] nanotransfer printing (nTP), [ 11 ] microcontact printing ( μ CP), [ 12 ] and micromolding in capillaries (MIMIC), [ 13 ] provide simple and inexpensive routes to fabricate complex multidimensional nanostructures. Above all, proximity fi eld nanopatterning (PnP), [ 14 ] which uses elastomeric components similar to those used in soft lithography, can generate complex 3D nanostructures very rapidly over large areas. Optical interference from the conformable elastomers, working as phase shift elements, generates a complex 3D intensity distribution by the Talbot effect, [ 15 ] or self-imaging effect. The diffracted images of surface relief structures are periodically repeated at integer or fractional Talbot distances from the surface of the mask.Pattern resolution in soft lithography is mainly determined by the fi neness and the aspect ratio of elastomeric surface relief structures, which generally consist of poly(dimethylsiloxane) (PDMS), from a Si master that contains the desired relief patterns on its surface. The height of the relief structures is particularly important in PnP because it defi nes the magnitude of the phase shift as a function of the refractive index and the wavelength of the incident light. [ 16 ] Hence, relief structures with a high aspect ratio and narrow spacings ( < 1 μ m) between features must be well-controlled (i.e., straightness, duty cycle). Currently, two critical issues complicate control of these requirements. The fi rst issue is the limited thickness and physical damage of a patterned photoresist on a Si wafer that serves as a master; a thicker resist can lead to greater diffi culty and a higher potential for damage during the photopatterning and replication processes. The second issue is the low Young's modulus of soft elastomers ( ≈ 2-9 MPa), [ 17 ] which causes a collapse or a break in the neck of elastomeric relief structures, even after fi ne replication from the master. The low mechanical property also results in problems such as surface wrinkling, [ 18 ] sagging, buckling, and deforming [ 19 , 20 ] of the elastomers. Thus, reproducibility of the patterning cannot be guaranteed when using conformal contact-dependent methods. Several mold materials, such as polyolefi n, [ 21 ] modifi ed polyurethane, [ 22 ] PDMS, [ 23 , 24 ] and perfl uoropolyether (PFPE), [ 25 ] have been proposed to increase the Young's modulus and aspect ratio of the relief structures. Nevertheless, dense and fi ne relief structures with a high aspect ratio compose...
Nanotransfer printing (nTP) has attracted considerable attention due to its good pattern resolution, process simplicity, and cost-effectiveness. However, the development of a large-area nTP process has been hampered by critical reliability issues related to the uniform replication and regular transfer printing of functional nanomaterials. Here, we present a very practical thermally assisted nanotransfer printing (T-nTP) process that can easily produce well-ordered nanostructures on an 8-inch wafer via the use of a heat-rolling press system that provides both uniform pressure and heat. We also demonstrate various complex pattern geometries, such as wave, square, nut, zigzag, and elliptical nanostructures, on diverse substrates via T-nTP. Furthermore, we demonstrate how to obtain a high-density crossbar metal-insulator-metal memristive array using a combined method of T-nTP and directed self-assembly. We expect that the state-of-the-art T-nTP process presented here combined with other emerging patterning techniques will be especially useful for the large-area nanofabrication of various devices.
This study evaluated how various porcine sires affected muscle fibre characteristics, with respect to production traits. Sires from Berkshire, Duroc, Meishan, and Yorkshire pigs were mated to Meishan dams (BM, DM, MM, and YM offspring, respectively). A total of 96 pigs were evaluated for muscle fibre characteristics and production traits. The progeny from Duroc and Yorkshire sires had the greatest number of total fibres (P<0.05) and exhibited less backfat thickness (P<0.001) and larger loin muscle areas (P<0.05) than BM pigs. The DM and BM crossbreds showed higher marbling (P<0.01), and colour scores (P<0.05), as well as lower shear force scores (P<0.001). The MM pigs had greater proportional area of type IIb muscle fibres (P<0.05), and also displayed higher drip loss (P<0.01), higher lightness (P<0.001), and a greater incidence of PSE pork (pale, soft, and exudative; 25%) than DM, BM, and YM. These results showed that a greater number of total muscle fibres without increasing the cross sectional area of fibres improved lean meat production, and that a lower proportion of type IIb fibres was associated with better meat quality. For these reasons, the Duroc sire × Meishan dam crossbreed emerged as the most appropriate mating type examined herein to simultaneously enhance both lean meat production and meat quality.
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