The development and initial demonstration of a scanned-wavelength, first-harmonic-normalized, wavelength-modulation spectroscopy with nf detection (scanned-WMS-nf/1f) strategy for calibration-free measurements of gas conditions are presented. In this technique, the nominal wavelength of a modulated tunable diode laser (TDL) is scanned over an absorption transition to measure the corresponding scanned-WMS-nf/1f spectrum. Gas conditions are then inferred from least-squares fitting the simulated scanned-WMS-nf/1f spectrum to the measured scanned-WMS-nf/1f spectrum, in a manner that is analogous to widely used scanned-wavelength direct-absorption techniques. This scanned-WMS-nf/1f technique does not require prior knowledge of the transition linewidth for determination of gas properties. Furthermore, this technique can be used with any higher harmonic (i.e., n>1), modulation depth, and optical depth. Selection of the laser modulation index to maximize both signal strength and sensitivity to spectroscopic parameters (i.e., gas conditions), while mitigating distortion, is described. Last, this technique is demonstrated with two-color measurements in a well-characterized supersonic flow within the Stanford Expansion Tube. In this demonstration, two frequency-multiplexed telecommunication-grade TDLs near 1.4 μm were scanned at 12.5 kHz (i.e., measurement repetition rate of 25 kHz) and modulated at 637.5 and 825 kHz to determine the gas temperature, pressure, H2O mole fraction, velocity, and absorption transition lineshape. Measurements are shown to agree within uncertainty (1%-5%) of expected values.
A two-color absorption spectroscopy strategy has been developed for measuring the column density and density-weighted path-average temperature of the absorbing species in nonuniform gases. This strategy uses two transitions with strengths that scale nearly linearly with temperature. In addition, measured lineshapes are used to accurately model absorbance spectra. As a result, the column density and density-weighted path-average temperature of the absorbing species can be inferred from a comparison of signals measured across a nonuniform line of sight (LOS) with simulated signals calculated using a uniform LOS. This strategy is demonstrated with simulations of water-vapor absorption across a nonuniform LOS with temperature and composition gradients comparable to those in hydrogen-air diffusion flames. In this demonstration, both the column density and density-weighted path-average temperature of water vapor are recovered to within 0.5%.
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