Carbon-based nanomaterials have rapidly advanced over the last few decades. Fullerenes, carbon nanotubes, graphene and its derivatives, graphene oxide, nanodiamonds, and carbon-based quantum dots have been developed and intensively studied. Among them, fullerenes have attracted increasing research attention due to their unique chemical and physical properties, which have great potential in a wide range of applications. In this article, we offer a comprehensive review of recent progress in the synthesis and the chemical and physical properties of fullerenes and related composites. The review begins with the introduction of various methods for the synthesis of functionalized fullerenes. A discussion then follows on their chemical and physical properties. Thereafter, various intriguing applications, such as using carbon nanotubes as nanoreactors for fullerene chemical reactions, are highlighted. Finally, this review concludes with a summary of future research, major challenges to be met, and possible solutions.

Graphene/hBN heterostructures can be considered as one of the basic building blocks for the next-generation optoelectronics mostly owing to the record-high electron mobilities. However, currently, the studies of the intrinsic optical properties of graphene are limited to the standard substrates (SiO2/Si, glass, quartz) despite the growing interest in graphene/hBN heterostructures. This can be attributed to a challenging task of the determination of hBN’s strongly anisotropic dielectric tensor in the total optical response. In this study, we overcome this issue through imaging spectroscopic ellipsometry utilizing simultaneous analysis of hBN’s optical response with and without graphene monolayers. Our technique allowed us to retrieve the optical constants of graphene from graphene/hBN heterostructures in a broad spectral range of 250–950 nm. Our results suggest that graphene’s absorption on hBN may exceed the one of graphene on SiO2/Si by about 60%.