A method to shape thin polymer films into periodic array of lenses is presented. A liquid layer placed on top of a much thinner polymer film is exposed to a transverse temperature gradient. The upper liquid layer undergoes the short-wavelength Bénard-Marangoni instability, which leads to periodic shear stresses at the liquid-liquid interface and corresponding interfacial deformations. The structures formed are solidified by curing with ultraviolet light. In comparison to previously reported single-layer patterning techniques, the presented method achieves structures of very high horizontal planform symmetry (highly ordered structures). Furthermore, other shapes of technical interest can be easily fabricated by engineering the temperature distribution at the liquid-gas interface.
The coupled dynamics of two conjugated liquid layers of disparate thicknesses, which coat a solid substrate and are subjected to a transverse temperature gradient, is investigated. The upper liquid layer evolves under the short-wavelength (SW) Bénard-Marangoni (BM) instability, whereas the lower, much thinner film undergoes a sheardriven long-wavelength deformation. Although the lubricating film should reduce the viscous stresses acting on the up to one hundred times thicker upper layer by only 10%, it is found that the critical Marangoni number of marginal stability may be as low as if a stress-free boundary condition were applied at the bottom of the upper layer, i.e. much lower than the classical value of 79.6 known for a single film. Furthermore, it is experimentally verified that the deformation of the liquid-liquid interface, albeit small, has a non-negligible effect on the temperature distribution along the liquid-gas interface of the upper layer. This stabilizes the hexagonal pattern symmetry towards external disturbances and indicates a two-way coupling of the different layers. The experiments also demonstrate how convection patterns formed in a liquid film can be used to pattern a second conjugated film. The experimental findings are verified by a numerical model of the coupled layers.
A novel approach to calibrate the sensitivity of a differential thermometer, consisting of several thermocouples connected in series (thermopile), has been developed. The goal of this method is to increase the accuracy of small temperature difference measurements (∆T ≤ 1 K), without invoking higher sensor complexity. To this end, a method to determine the optimal temperature difference employed during the differential measurement of thermoelectric sensitivities has been developed. This calibration temperature difference is found at the minimum of combined measurement and linearization error for a given mean temperature. The developed procedure is demonstrated in an illustrative example calibration of a nine-junction thermopile. For mean temperatures between −10 • C and 15 • C, the thermoelectric sensitivity was measured with an uncertainty of less than ±2 %. Subsequently, temperature differences as low as 0.01 K can be resolved, while the thermometer used for the example calibration was accurate only to ±0.3 K. This and higher degrees of accuracy are required in certain research applications, for example to detect heat flux modulations in bifurcating fluidic systems.
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