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The aim of this study is to understand the limitation of organic pollutant indexes (BOD5, CODMn, CODCr) and estimate to set the TOC standard by comparing oxidation rates of BOD5, CODMn, CODCr and TOC based on the 487 organic compounds and 11 effluents from industrial wastewater containing various and unknown organic compounds. The range of ratio of theoretical oxygen demand (ThOD) to theoretical organic carbon (TOCt) was 0.00~5.33 and average ratio of classes of organic compounds was 2.68~3.70. According to classes of organic compounds, the average ratio of O2/C was 1.2 (range : 1.02~1.39). The order of oxidation rate for 15 organic compounds was TOC (90.7%) > CODCr (88.8%) > BOD5 (54.4%) > CODMn (30.8%) indicating the lower oxidation rate of BOD5 and COD compared with TOC. The ranking for average oxidation rate was CODCr > CODMn > BOD5 indicating that BOD5, CODMn could be underestimated comparing with ThOD of organic compounds in case of industrial wastewater containing high concentration of refractory organic compounds. Most of the relationships between organic pollutant indexes and TOC were higher than 0.9. The ratio of TOC to organic compound indexes decreased in the order : CODCr (3.4) > CODMn (1.9) > BOD5 (0.7).

During the summer rainy season, double thermoclines were observed in a small canyon-shaped reservoir. The physical processes leading to thermocline evolution are examined from the vertical temperature profile observed along the reservoir before and after rain. Observations show that their evolution is related to the inflow of runoff, which is colder than the reservoir surface water and post-rain fair-weather conditions. Tongue-like distributions of turbidity, conductivity and nutrient concentrations downstream from the headwater clearly reveal the presence of runoff-induced intermediate inflows. In addition to supplying nutrients, the inflow provides the oxygen-deficient intermediate layer with a rich supply of dissolved oxygen. Concurrently, in the upper part of the reservoir runoff-induced inflows may drive the oxygen-deficient bottom water to shift downstream along the layer beneath the runoff-induced inflow. The water mass between the two thermoclines may operate as a source of nutrients for algal development in early autumn when the upper thermocline is destroyed by the convective overturn owing to the surface cooling.

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In Korea, the chemical oxygen demand(CODsed) in freshwater sediments has been measured by the potassium permanganate method used for marine sediment because of the absence of authorized analytical method. However, this method has not been fully verified for the freshwater sediment. Therefore, the use or modification of the potassium permanganate method or the development of the new CODsed analytical method may be necessary. In this study, two modified CODsed analytical methods such as the modified potassium permanganate method for CODMn and the modified closed reflux method using potassium dichromate for CODCr were compared. In the preliminary experiment to estimate the capability of the two oxidants for glucose oxidation, CODMn and CODCr were about 70% and 100% of theoretical oxygen demand(ThOD), respectively, indicating that CODCr was very close to the ThOD. The effective titration ranges in CODMn and CODCr were 3.2 to 7.5 mL and 1.0 to 5.0 mL for glucose, 4.3 to 7.5 mL and 1.4 to 4.3 mL for lake sediment, and 2.5 to 5.8 mL and 3.6 to 4.5 mL for river sediment, respectively, within 10% errors. For estimating CODsed recovery(%) in glucose-spiked sediment after aging 1)