Thermal annealing of a polymer light-emitting diode (PLED) is shown to result in a remarkable improvement in the long-term stability of the device. The annealing for such a PLED has to be layer-specific in that the annealing should be carried out for the layer with the lowest glass transition temperature (Tg) to harvest the benefits of annealing. Annealing of this key layer, which is usually the emitting layer, can enhance the thermal stability of the device. The best half-life is obtained at an annealing temperature above the Tg of emitting polymer. It is shown that the annealing of the emitting polymer layer results in a more than an order of magnitude increase in the half-life, in spite of a decrease in the efficiency of the device as the annealing temperature increases.
A fast switching electro-optic device, based upon the in-plane addressing of very short pitch polymer stabilized chiral nematic liquid crystals, is presented. Polymer stabilization of the standing helical arrangement is essential to prevent the appearance of defects above the in-plane electrodes. Response times as short as 50 μs are observed at room temperature along with contrast ratios greater than 3000:1 owing to the high optical extinction at visible wavelengths in the “Off” state. The combination of these fast response times with such high contrast ratios is of great importance for next generation electro-optical elements.
The preparation, characterization, and properties of the new thermoplastic vulcanizate (TPV)/organoclay nanocomposites are reported in this article. The nanocomposites were prepared by the melt intercalation method. The organoclay was first treated with glycidyl methacrylate, which acts as a swelling agent for organoclays, as well as a grafting agent for TPV (in the presence of dicumyl peroxide) during the melt mixing. The nanocomposite was intercalated, as evidenced by X-ray diffraction. The tensile modulus of the 5% TPV/organoclay nanocomposite was higher than that of the 20% talc-filled microcomposite. The storage modulus of the nanocomposite was higher than that of the pristine TPV. The most important observation is obtained from dynamic mechanical analysis, which reveals that the glass-transition temperature of the polypropylene phase of the nanocomposite increases (as compared to virgin TPV), whereas the ethylene-propylene-diene monomer phase remains almost the same.
This is the first report on real XGA AMLCD for NBPC with highly stable integrated gate driver circuits using a-Si TFT. The new circuit has been designed with dual-pull down structure for high reliability and has been working for over 2,000 hours at 60 o C, which is sufficient working time for normal driving conditions.
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