Abstract. We present 60 years of 14 CO 2

<p><strong>Abstract.</strong> We present 60 years of Δ<sup>14</sup>CO<sub>2</sub> measurements from Wellington, New Zealand (41° S, 175° E). The record has been extended and fully revised. New measurements have been used to evaluate the existing record and to replace original measurements where warranted. This is the earliest atmospheric Δ<sup>14</sup>CO<sub>2</sub> record and records the rise of the <sup>14</sup>C "bomb spike", the subsequent decline in Δ<sup>14</sup>CO<sub>2</sub> as bomb <sup>14</sup>C moved throughout the carbon cycle and increasing fossil fuel CO<sub>2</sub> emissions further decreased atmospheric Δ<sup>14</sup>CO<sub>2</sub>. The initially large seasonal cycle in the 1960s reduces in amplitude and eventually reverses in phase, resulting in a small seasonal cycle of about 2 ‰ in the 2000s. The seasonal cycle at Wellington is dominated by the seasonality of cross-tropopause transport, and differs slightly from that at Cape Grim, Australia, which is influenced by anthropogenic sources in winter. Δ<sup>14</sup>CO<sub>2</sub> at Cape Grim and Wellington show very similar trends, with significant differences only during periods of known measurement uncertainty. In contrast, Northern Hemisphere clean air sites show a higher and earlier bomb <sup>14</sup>C peak, consistent with a 1.4-year interhemispheric exchange time. From the 1970s until the early 2000s, the Northern and Southern Hemisphere Δ<sup>14</sup>CO<sub>2</sub> were quite similar, apparently due to the balance of <sup>14</sup>C-free fossil fuel CO<sub>2</sub> emissions in the north and <sup>14</sup>C-depleted ocean upwelling in the south. The Southern Hemisphere sites show a consistent and marked elevation above the Northern Hemisphere sites since the early 2000s, which is most likely due to reduced upwelling of <sup>14</sup>C-depleted and carbon-rich deep waters in the Southern Ocean. This developing Δ<sup>14</sup>CO<sub>2</sub> interhemispheric gradient is consistent with recent studies that indicate a reinvigorated Southern Ocean carbon sink since the mid-2000s, and suggests that upwelling of deep waters plays an important role in this change.</p>

<p>This study demonstrates the utility of tree ring radiocarbon analysis to quantify a temporal record of recently-added fossil fuel-derived carbon dioxide (CO₂ff) in the urban atmosphere, to retrospectively measure emissions and potentially validate local emissions inventories. Currently, there is no internationally recognised method to test emissions inventories against direct atmospheric estimations of CO₂ff. With the increasing interest in emissions control legislation, independent and objective research to validate emissions reported by governments and industries is needed.  As CO₂ff emissions are completely depleted in radiocarbon (¹⁴C), an observed decrease in the ¹⁴C content of the atmosphere is mostly due to additions of CO₂ff. As trees incorporate CO₂ from the local atmosphere into annual growth rings, it was hypothesised that an urban located tree would reflect emission rates of its local surroundings. Measurements of the ¹⁴C content of cellulose were made from the annual tree rings of a Kauri tree (Agathis australis), located in the downtown area of the Wellington suburb of Lower Hutt (KNG52). This record was compared with tree rings from two Kauri at a nearby coastal site (NIK19 and NIK23) and the long-term clean air ¹⁴CO₂ record from Baring Head. The clean air Kauri trees, NIK19 and NIK23, demonstrated excellent agreement with the Baring Head atmospheric record, indicating that the trees were accurately sampling the atmosphere. The KNG52 tree, demonstrated good agreement with the clean air record in the early part of the record (with some variability), however, exhibited significantly lower Δ¹⁴CO₂ values from the 1980s onward. Calculation of the influence of the terrestrial biosphere on the ¹⁴CO₂ record showed very little impact, determining that the variability seen was due to local additions of CO₂ff.  Historic CO₂ff emissions were calculated using the Δ¹⁴CO₂ measurements from the KNG52 ¹⁴CO₂ record for the period 1972 – 2012. Biosphere correction calculations showed that the biosphere was the dominant influence on the record in the early part of the record (1972 – 1980), with fossil fuel emissions dominating the record from 1980s onward. The observations were compared qualitatively with meteorological data and urban development in the area to assess variability in CO₂ff. A minor trend towards lower wind speeds associated with higher levels of CO₂ff was identified, indicating that local meteorology may be responsible for 10% change seen in the record. The influence of local development demonstrated some possible relation but a correlation was not significant. The KNG52 CO₂ff record was compared with national-level reported liquid (road traffic) emissions from the Carbon Dioxide Information Analysis Centre (CDIAC). The observed KNG52 CO₂ff in the tree ring record appeared to increase in tandem with road traffic emissions.</p>

No abstract

<p>This study demonstrates the utility of tree ring radiocarbon analysis to quantify a temporal record of recently-added fossil fuel-derived carbon dioxide (CO₂ff) in the urban atmosphere, to retrospectively measure emissions and potentially validate local emissions inventories. Currently, there is no internationally recognised method to test emissions inventories against direct atmospheric estimations of CO₂ff. With the increasing interest in emissions control legislation, independent and objective research to validate emissions reported by governments and industries is needed.  As CO₂ff emissions are completely depleted in radiocarbon (¹⁴C), an observed decrease in the ¹⁴C content of the atmosphere is mostly due to additions of CO₂ff. As trees incorporate CO₂ from the local atmosphere into annual growth rings, it was hypothesised that an urban located tree would reflect emission rates of its local surroundings. Measurements of the ¹⁴C content of cellulose were made from the annual tree rings of a Kauri tree (Agathis australis), located in the downtown area of the Wellington suburb of Lower Hutt (KNG52). This record was compared with tree rings from two Kauri at a nearby coastal site (NIK19 and NIK23) and the long-term clean air ¹⁴CO₂ record from Baring Head. The clean air Kauri trees, NIK19 and NIK23, demonstrated excellent agreement with the Baring Head atmospheric record, indicating that the trees were accurately sampling the atmosphere. The KNG52 tree, demonstrated good agreement with the clean air record in the early part of the record (with some variability), however, exhibited significantly lower Δ¹⁴CO₂ values from the 1980s onward. Calculation of the influence of the terrestrial biosphere on the ¹⁴CO₂ record showed very little impact, determining that the variability seen was due to local additions of CO₂ff.  Historic CO₂ff emissions were calculated using the Δ¹⁴CO₂ measurements from the KNG52 ¹⁴CO₂ record for the period 1972 – 2012. Biosphere correction calculations showed that the biosphere was the dominant influence on the record in the early part of the record (1972 – 1980), with fossil fuel emissions dominating the record from 1980s onward. The observations were compared qualitatively with meteorological data and urban development in the area to assess variability in CO₂ff. A minor trend towards lower wind speeds associated with higher levels of CO₂ff was identified, indicating that local meteorology may be responsible for 10% change seen in the record. The influence of local development demonstrated some possible relation but a correlation was not significant. The KNG52 CO₂ff record was compared with national-level reported liquid (road traffic) emissions from the Carbon Dioxide Information Analysis Centre (CDIAC). The observed KNG52 CO₂ff in the tree ring record appeared to increase in tandem with road traffic emissions.</p>