Considerable amounts of polycyclic aromatic hydrocarbons (PAH) are present in the workplace. In order to obtain a better understanding of the occupational hazards connected with PAH exposure various biomonitoring methods need to be applied. The level of PAH in urine collected from coke-oven workers has been measured by a recently developed radioimmunoassay. A significant correlation between estimated exposure levels for PAH and urinary levels of PAH was observed. During the winter period the control group was found to have an average concentration of 0.44 ng PAH/mmol creatinine, whereas the low, medium and high exposure groups contained 0.44, 0.71 and 0.85 ng PAH/mmol creatinine respectively. The urinary PAH level in the samples collected during the summer period was higher, i.e. 0.81, 0.94 and 1.10 ng PAH/mmol creatinine, for the low, medium and high exposure groups. Furthermore, a correlation was also observed between smoking and levels of urinary PAH. We conclude that this radioimmunoassay may be suitable as a simple and sensitive routine assay for monitoring individuals exposed to PAH.
The emission of particles and organic micropollutants (PAH, PCDD and PCDF) was measured from three intermittently operated municipal waste incinerators of medium size. The mutagenicity of the stack gas samples were measured as well. The results show a good agreement between the PAH emitted and the mutagenicity in the stack gases, but none of these parameters correlate with the PCDD/PCDF content.
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