We present a method for measuring magnetic field gradients with macroscopic singlet states realized with ensembles of spin-j particles. While the singlet state is completely insensitive to homogeneous magnetic fields, the variance of its collective spin components is highly sensitive to field gradients. We compute the dynamics of this variance analytically for a chain of spins and also for an ensemble of particles with a given density distribution. We find an upper bound on how precisely the field gradient can be estimated from the measured data. Based on our calculations, differential magnetometry can be carried out with cold atomic ensembles using a multipartite singlet state obtained via spin squeezing. On the other hand, comparing the metrological properties of the experimentally prepared state to that of the ideal singlet can be used as further evidence that a singlet state has indeed been created.Comment: 15 pages including 5 figures + 7 pages supplement, revtex4; published versio

We study gradient magnetometry with an ensemble of atoms with arbitrary spin. We calculate precision bounds for estimating the gradient of the magnetic field based on the quantum Fisher information. For quantum states that are invariant under homogeneous magnetic fields, we need to measure a single observable to estimate the gradient. On the other hand, for states that are sensitive to homogeneous fields, a simultaneous measurement is needed, as the homogeneous field must also be estimated. We prove that for the cases studied in this paper, such a measurement is feasible. We present a method to calculate precision bounds for gradient estimation with a chain of atoms or with two spatially separated atomic ensembles. We also consider a single atomic ensemble with an arbitrary density profile, where the atoms cannot be addressed individually, and which is a very relevant case for experiments. Our model can take into account even correlations between particle positions. While in most of the discussion we consider an ensemble of localized particles that are classical with respect to their spatial degree of freedom, we also discuss the case of gradient metrology with a single Bose-Einstein condensate.

We consider a number operator-annihilation operator uncertainty as a well behaved alternative to the number-phase uncertainty relation, and examine its properties. We find a formulation in which the bound on the product of uncertainties depends on the expectation value of the particle number. Thus, while the bound is not a constant, it is a quantity that can easily be controlled in many systems. The uncertainty relation is approximately saturated by number-phase intelligent states. This allows us to define amplitude squeezing, connecting coherent states to Fock states, without a reference to a phase operator. We propose several setups for an experimental verification.PACS numbers: 03.65. Fd, 42.50.Dv For the two-mode system, inequalities similar to Eqs. (10) and (2) can be found using the Schwinger rep-